History of Organometallic Polymers

Sheats, John E.

doi:10.1080/00222338108066460

Cited by 14 publications

(2 citation statements)

References 34 publications

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“…Sheats prewhich metal ion may suitably be coordinated [9][10][11][12] ; sented the history of organometallic polymers. 1 and (3) a metal ion may be coordinated with a Some extensive reviews have appeared on metalligand and the monomeric metal complex may recontaining polymers. [2][3][4][5][6] act with another organic compound to form a polymeric complex.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of coordination polymers of polyesters with pendant amino groups

Bajpai¹,

Rai

1998

J. Appl. Polym. Sci.

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Oligomeric polyester, namely, poly(tetramethylene aspartate) (PTMA), was synthesized from D,L-aspartic acid and 1,4-butanediol by a melt-condensation technique. Polyester-metal complexes were synthesized by the reaction of PTMA with hydrated acetates of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Mg(II), Ca(II), Pb(II), and Ce(IV) in DMSO. The polyester-metal complexes were characterized by elemental analysis, IR spectral studies, magnetic susceptibility measurements, and thermogravimetry. The metal ions were found to be six-coordinated with two water molecules as additional ligands besides oxygen and nitrogen atoms of polyester repeating units. Thermogravimetric analysis (TGA) showed that coordination polymers are thermally more stable than is polyester.

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Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of coordination polymers of polyesters with pendant amino groups

Bajpai¹,

Rai

1998

J. Appl. Polym. Sci.

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“…In other words, such products are a variety of polymer-immobilized catalysts fixed on polymers as macroligands (Refs. [1][2][3][4]. However, in contrast to the synthesis via macroligands, they can be obtained by a one-pot synthesis: polymerization and copolymerization of MCMs.…”

Section: Introductionmentioning

confidence: 99%

(Co)polymerization of metal‐containing monomers as a way of MMC synthesis

Pomogailo

1998

Macromolecular Symposia

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The principal advances and problems of the synthesis, of poly‐, co‐ and graft‐ polymerization of metal‐containing monomers (MCM) are analysed. The MCMs are classified on the type of the metal bond with the organic part of the molecule, viz. MCM with σ‐, nv‐, and π‐bonds. The effect of a transition metal on both the polymerization and on the properties of the products formed is of special interest. The basic fields of application of metal‐containing polymers have been summed up.

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Polymerization of Metal‐Containing Monomers (MCMs) as a Method for Incorporating Metals in Macromolecules

Pomogailo

2003

Metal Complexes and Metals in Macromolecules

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History of Organometallic Polymers

Cited by 14 publications

References 34 publications

Synthesis and characterization of coordination polymers of polyesters with pendant amino groups

Synthesis and characterization of coordination polymers of polyesters with pendant amino groups

(Co)polymerization of metal‐containing monomers as a way of MMC synthesis

Polymerization of Metal‐Containing Monomers (MCMs) as a Method for Incorporating Metals in Macromolecules

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