Historiens Et Démographes

Catalytic and Kinetic Waves in Polarography

“…N. Frumkin was the first to consider the effect of the double-Iayer structure on the kinetics of electrochemical processes in developing the theory of slow discharge and hydrogen overpotential [7,8,551]. Frumkin 's views were later fruitfully employed by himself and by his co-workers to explain the phenomena observed in the electrochemical reduction of oxygen [552], anions [463][464][465][466][551][552][553][554][555][556][557][558][559], and several neutral compounds.…”

“…N. Frumkin was the first to consider the effect of the double-Iayer structure on the kinetics of electrochemical processes in developing the theory of slow discharge and hydrogen overpotential [7,8,551]. Frumkin 's views were later fruitfully employed by himself and by his co-workers to explain the phenomena observed in the electrochemical reduction of oxygen [552], anions [463][464][465][466][551][552][553][554][555][556][557][558][559], and several neutral compounds. Recently, the ideas developed by Frumkin have become widespread among electrochemists (see, for example, [420,[560][561][562]); several publications have appeared in which the effect of the double-Iayer structure on electrode processes was discussed.…”