Production of electricity by friction is well known but poorly understood and it is the source of electrostatic discharge causing serious accidents. Recent results are in agreement with one of the conflicting views on this problem, according to which triboelectricity in polymers is triggered by mechanochemical and wear or mass transfer phenomena. These results also challenge the widely accepted paradigm of one-way charge transfer that is the basis of the triboelectric series. Experimental results from powerful analytical techniques 10 65 mechanisms leading to solids contact electrification and/or triboelectric charging? The explanation of the production of electrostatic charge comes from a transfer of electrons, ions or both, which are presented in the literature? 16 Poor knowledge on charge accumulation and dissipation 70 mechanisms 17-19 is a root of large-scale personal and property losses, including serious industrial accidents and explosions that are described further in the next section. This is ultimately due to the lack of scientific understanding of the basic phenomena.On the other hand, fundamental electrostatic concepts are well 75 established for semiconductors and metals. 20 When two metals with different work functions are brought into contact, electrons migrate across the interface creating a potential difference between them.