2015
DOI: 10.1016/j.actbio.2015.01.037
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Highly-translucent, strong and aging-resistant 3Y-TZP ceramics for dental restoration by grain boundary segregation

Abstract: Latest trends in dental restorative ceramics involve the development of full-contour 3Y-TZP ceramics which can avoid chipping of veneering porcelains. Among the challenges are the low translucency and the hydrothermal stability of 3Y-TZP ceramics. In this work, different trivalent oxides (Al2O3, Sc2O3, Nd2O3 and La2O3) were selected to dope 3Y-TZP ceramics. Results show that dopant segregation was a key factor to design hydrothermally stable and high-translucent 3Y-TZP ceramics and the cation dopant radius cou… Show more

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Cited by 132 publications
(111 citation statements)
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References 49 publications
(67 reference statements)
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“…A large trivalent dopant, oversized as compared to Zr4+, exhibiting strong segregation at the ZrO 2 grain boundary was preferred. The introduction of 0.2 mol% La 2 O 3 in conventional Al2O3 -doped 3Y-TZP resulted in an unique combination of high translucency (42% increase compared to conventional 0.25 wt.% alumina-doped 3Y-TZP) and superior hydrothermal stability (no transformation up to 120 h of hydrothermal aging at 134 _C), while maintaining excellent mechanical properties (22).…”
Section: Resultsmentioning
confidence: 99%
“…A large trivalent dopant, oversized as compared to Zr4+, exhibiting strong segregation at the ZrO 2 grain boundary was preferred. The introduction of 0.2 mol% La 2 O 3 in conventional Al2O3 -doped 3Y-TZP resulted in an unique combination of high translucency (42% increase compared to conventional 0.25 wt.% alumina-doped 3Y-TZP) and superior hydrothermal stability (no transformation up to 120 h of hydrothermal aging at 134 _C), while maintaining excellent mechanical properties (22).…”
Section: Resultsmentioning
confidence: 99%
“…20 An additional approach that can be used is to replace tetragonal zirconia grains with optically isotropic cubic zirconia particles by increasing the yttria content to diminish the grain boundary light scattering to yield fully stabilized zirconia. 21 (iii) The third generation, 4-5Y-PSZ, incorporates more optically isotropic cubic zirconia (50-80%), has a grain size of 1 to 4 μm and is produced by increasing the Y 2 O 3 dopants to 4 to 5 mol% and increasing the sintering temperature and/or duration more than that of the second generation. However, cubic zirconia is weaker and more brittle than its tetragonal counterpart, which jeopardizes the strength of the zirconia.…”
mentioning
confidence: 99%
“…According to some studies, increasing grain size by changing the sintering conditions can also decrease the opacity of full-contour Y-TZP ceramics 4,15,16) . However, these larger grains would lead to the metastabilization of the grains and low temperature degradation (LTD) 17,18) . Radiopacity is a valuable property that allows the clinician to assess the adequacy of the restoration, distinguish secondary caries, and evaluate marginal adaptation, voids, and interfacial gaps [19][20][21][22][23] .…”
Section: Introductionmentioning
confidence: 99%