Highly stable olefin–Cu(i) coordination oligomers and polymers

Abstract

Highly stable Cu(I)-olefin coordination oligomers and polymers have been successfully prepared and applied to construct metal-organic frameworks (MOFs) with interesting physical and chemical functions in recent years. In this review, we present the olefin-Cu(I) coordination oligomers and polymers and their novel physical properties. From structure to functions, particular emphasis is placed on the coordination and organometallic chemistry of olefin-Cu(I) coordination oligomers and polymers, their structures and potential applications as solids possessing unusual physical functional properties such as electrochemical, chiral separation, fluorescent sensing and ferroelectricity.

Competitive Equilibria in Atom Transfer Radical Polymerization

“…[54] The coordination of several monomers such as styrene, 1-octene, methyl acrylate, and methyl methacrylate to the Cu I /PMDETA complex with non-coordinating anions was recently reported. [55,56] Formation constants for these complexes (Table 1) were determined from variable temperature 1 H NMR experiments monitoring the free and complexed vinyl proton resonances.…”

Synthesis and Crystal Structure of Three New Zn(II), Ni(II) and Mn(II) Coordination Polymers Based on Asymmetric Dicarboxylate Ligand

“…Due to the intriguing variety of architecture and potential applications in luminescence, gas storage, molecular magnetism and ion exchange, the construction of metalorganic frameworks (MOFs) have attracted widespread interest in recent years [1][2][3][4][5][6][7][8][9][10][11][12]. Carboxylate ligands have been employed most often in the design and synthesis for MOFs because of their versatile linking capability in virtue of both covalent bonding and supramolecular interaction [13][14][15][16][17][18].…”

Design, structure and properties of a novel 3D metal-organic framework constructed from N-donor ligand supporting Cd(II)-carboxylate layer

“…The layers are supported by linear TED ligands as pillars along the c axis to build a 3D open-framework. Consequently, this complex could exhibit substantial water adsorption behavior and favorable fluorescent property as a polynuclear d 10 metal complex [25,26].…”

“…The layers are supported by linear TED ligands as pillars along the c axis to build a 3D open-framework. Consequently, this complex could exhibit substantial water adsorption behavior and favorable fluorescent property as a polynuclear d 10 metal complex [25,26].As a typical procedure, a mixture of CdCl 2 AE 2.5H 2 O, H 3 CTC and TED was dissolved in N,N-dimethylformamide(DMF)/ethanol/H 2 O, then was sealed and left undisturbed at 65°C for 3 days. The resulting colorless 1387-7003/$ -see front matter Ó…”