Highly sensitive optical waveguide sensor for SO<sub>2</sub> and H<sub>2</sub>S detection in the parts-per-trillion regime using tetraaminophenyl porphyrin

Maimaiti, Asiya; Abdurahman, Renagul; Kari, Nuerguli; Ma, Qingrong; Wumaier, Kediliya; Nizamidin, Patima; Abliz, Shawket; Yimit, Abliz

doi:10.1080/09500340.2020.1758817

Cited by 14 publications

(11 citation statements)

References 35 publications

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“…As dyes absorbing in the near-infrared (NIR), hyperporphyrins are clearly of interest in photomedicine, for example, as photosensitizers in photodynamic therapy. 9 − 13 Protonated porphyrins have been used as sensors for gases such as ammonia, hydrogen sulfide, and sulfur dioxide, 14 , 15 while H 2 [TAPP] has also been used as a building block for dye-sensitized solar cells. 16 − 18 Porphyrin protonation has also been used for pH 19 , 20 and anion sensing 21 and even for modulating the optical properties of metal–organic frameworks (MOFs).…”

Section: Introductionmentioning

confidence: 99%

Understanding Hyperporphyrin Spectra: TDDFT Calculations on Diprotonated Tetrakis(p-aminophenyl)porphyrin

2021

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A detailed TDDFT study (with all-electron STO-TZ2P basis sets and the COSMO solvation model) has been carried out on the effect of diprotonation on the UV−vis−NIR spectra of free-base tetraphenylporphyrin and tetrakis(p-aminophenyl)porphyrin. The diprotonated forms have been modeled as their bis-formate complexes, i.e., as so-called porphyrin diacids. The dramatic redshift of the Q-band of the TAPP diacid has been explained in terms of an elevated "a 2u " HOMO and lowered LUMOs, both reflecting infusion of aminophenyl character into the otherwise classic Gouterman-type frontier MOs. The exercise has also yielded valuable information on the performance of different exchange− correlation functionals. Thus, the hybrid B3LYP functional was found to yield a substantially better description of key spectral features, especially the diprotonation-induced redshifts, than the pure OLYP functional. Use of the range-separated CAMY-B3LYP functional, on the other hand, did not result in improvements relative to B3LYP.

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Section: Introductionmentioning

confidence: 99%

Understanding Hyperporphyrin Spectra: TDDFT Calculations on Diprotonated Tetrakis(p-aminophenyl)porphyrin

2021

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“…For TAPP film ( Figure 6 b), no remarkable change in position of bands with CO 2 exposure; only a broadening of the Soret band was detected, which might be the result of the enlargement of the aggregated form of the porphyrins in film [ 24 ]. When TAPP was exposed to H 2 S and HCl, both Soret bands were blue shifted of 22 nm, while with NO 2 it broadened with bathochromic shift of 25 nm.…”

Section: Resultsmentioning

confidence: 99%

“…Researchers reported porphyrin films with various functional groups to detect H 2 S gas at room temperature with [ 22 , 23 , 24 , 25 , 26 , 27 ] using optical waveguide but the results and experimental performance are deficient in consistence. Therefore, in this work, we consolidate the experimental performing conditions including film width and thickness that was controlled by film fabrication velocity and solution concentration; laser light wavelength (670 nm), gas concentration was also unified to keep the only possible different variable is the influence of functional groups.…”

Section: Resultsmentioning

confidence: 99%

“…Several dyes and pH indicators were studied to detect organic volatiles and inorganic vapors using optical waveguide system [ 16 , 17 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 ]. Herein, influence of substituents on porphyrin molecules to the sensitivity and selectivity has been analyzed with molecular dynamic simulation (MDS).…”

Section: Introductionmentioning

confidence: 99%

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Substituent Effect on Porphyrin Film-Gas Interaction by Optical Waveguide: Spectrum Analysis and Molecular Dynamic Simulation

et al. 2020

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Substituent effect on optical gas sensing performance in porphyrin-based optical waveguide detection system was studied by molecular dynamics simulation (MDS), absorption/emission spectrum analysis, and optical waveguide (OWG) detection. The affinities of porphyrin with seven types of substituents (–H, –OH, –tBu, –COOH, –NH2, –OCH3, –SO3−) on para position of meso-phenyl porphyrin toward gas molecules in adsorption process were studied in different size of boxes with the same pressure and concentration. Analyte gases (CO2, H2S, HCl, NO2) were exposed to porphyrin film in absorption spectrophotometer, and in OWG with evanescent field excited by a guiding laser light with 670 nm wavelength. The extent of interaction between host molecule and the guest analytes was analyzed by the number of gas molecules in vicinity of 0.3 nm around substituents of porphyrin molecules. Optical waveguide results reveal that sulfonate porphyrin is mostly responsive to hydrochloride, hydrosulfide gas and nitrogen dioxide gases with strong response intensity. Molecular dynamics and spectral analysis provide objective information about the molecular state and sensing properties. Molecular rearrangements induced by gas exposure was studied by spectral analysis and surface morphology before and after gas exposure taking hydrosulfide gas as an example. Film-gas interaction mechanism was discussed in terms of each gas and substituent group characters.

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“…A variety of gas sensors such as electrochemical [2,3], piezoelectric [4], metal oxide semiconductor-based [5][6][7], micro-electromechanical based system [8], and optical waveguide (OWG) sensors [9,10] have been developed to detect H 2 S gas.…”

Section: Introductionmentioning

confidence: 99%

Zinc Phthalocyanine Thin Film-Based Optical Waveguide H2S Gas Sensor

Wumaier

Mamtmin

et al. 2021

Photonic Sens

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The detection of hydrogen sulfide (H2S) is essential because of its toxicity and abundance in the environment. Hence, there is an urgent requisite to develop a highly sensitive and economical H2S detection system. Herein, a zinc phthalocyanine (ZnPc) thin film-based K+-exchanged optical waveguide (OWG) gas sensor was developed for H2S detection by using spin coating. The sensor showed excellent H2S sensing performance at room temperature with a wide linear range (0.1 ppm–500 ppm), reproducibility, stability, and a low detection limit of 0.1 ppm. The developed sensor showed a significant prospect in the development of cost-effective and highly sensitive H2S gas sensors.

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Highly sensitive optical waveguide sensor for SO₂ and H₂S detection in the parts-per-trillion regime using tetraaminophenyl porphyrin

Cited by 14 publications

References 35 publications

Understanding Hyperporphyrin Spectra: TDDFT Calculations on Diprotonated Tetrakis(p-aminophenyl)porphyrin

Understanding Hyperporphyrin Spectra: TDDFT Calculations on Diprotonated Tetrakis(p-aminophenyl)porphyrin

Substituent Effect on Porphyrin Film-Gas Interaction by Optical Waveguide: Spectrum Analysis and Molecular Dynamic Simulation

Zinc Phthalocyanine Thin Film-Based Optical Waveguide H2S Gas Sensor

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Highly sensitive optical waveguide sensor for SO2 and H2S detection in the parts-per-trillion regime using tetraaminophenyl porphyrin

Cited by 14 publications

References 35 publications

Understanding Hyperporphyrin Spectra: TDDFT Calculations on Diprotonated Tetrakis(p-aminophenyl)porphyrin

Understanding Hyperporphyrin Spectra: TDDFT Calculations on Diprotonated Tetrakis(p-aminophenyl)porphyrin

Substituent Effect on Porphyrin Film-Gas Interaction by Optical Waveguide: Spectrum Analysis and Molecular Dynamic Simulation

Zinc Phthalocyanine Thin Film-Based Optical Waveguide H2S Gas Sensor

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Highly sensitive optical waveguide sensor for SO₂ and H₂S detection in the parts-per-trillion regime using tetraaminophenyl porphyrin