Highly selective hydrogenative ring-rearrangement of furfural to cyclopentanone over a bifunctional Ni3P/γ-Al2O3 catalyst

Yu, Zhiquan; Li, Yan; Yao, Yunlong; Wang, Yao; Liu, Ying‐Ya; Sun, Zhichao; Shi, Chuan; Wang, Wei; Wang, Anjie

doi:10.1016/j.mcat.2022.112239

Cited by 5 publications

(5 citation statements)

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“…49 And nano-Al 2 O 3 is a typical catalyst carrier, which can provide a good carrier for anaerobic medium and promote the occurrence of hydrogenation and redox. [50][51][52][53] In complex AD process, the effect of Al 2 O 3 as a carrier will be further research in the future.…”

Section: Discussionmentioning

confidence: 99%

Effect of nano-Al₂O₃ and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Zhao,

Cheng,

Zhao

et al. 2023

RSC Adv.

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Section: Discussionmentioning

confidence: 99%

Effect of nano-Al₂O₃ and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Zhao,

Cheng,

Zhao

et al. 2023

RSC Adv.

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“…Other Ni TMP and conventional Ni catalysts such as Ni NP, Raney Ni, Ni (0), and NiO, showed minimal catalytic activity in comparison to Ni 2 P. The control experiments were also done with various metal phosphides on different supports, out of which nickel phosphide supported on mordenite (Ni 2 P/mordenite) showed the best catalytic activity as shown in (Figure 18j,k). In addition, Yu et al [255] prepared a bifunctional Ni 3 P/gAl 2 O 3 which provides both metal site as well as Lewis acidic site for the selective hydrogenation of furfural to cyclopentanone. The increased catalytic activity of the Ni 3 P/gAl 2 O 3 is due to the homogeneous dispersion of Ni 3 P NP across the gAl 2 O 3 , which was confirmed via TEM investigation.…”

Section: Hydrogenation Of Alkenes and Alkynesmentioning

confidence: 99%

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

Sharma

Choudhary

Kumar

et al. 2023

Small

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Transition metal phosphides (TMP) posses unique physiochemical, geometrical, and electronic properties, which can be exploited for different catalytic applications, such as photocatalysis, electrocatalysis, organic catalysis, etc. Among others, the use of TMP for organic catalysis is less explored and still facing many complex challenges, which necessitate the development of sustainable catalytic reaction protocols demonstrating high selectivity and yield of the desired molecules of high significance. In this regard, the controlled synthesis of TMP‐based catalysts and thorough investigations of underlying reaction mechanisms can provide deeper insights toward practical achievement of desired applications. This review aims at providing a comprehensive analysis on the recent advancements in the synthetic strategies for the tailored and tunable engineering of structural, geometrical, and electronic properties of TMP. In addition, their unprecedented catalytic potential toward different organic transformation reactions is succinctly summarized and critically analyzed. Finally, a rational perspective on future opportunities and challenges in the emerging field of organic catalysis is provided. On the account of the recent achievements accomplished in organic synthesis using TMP, it is highly anticipated that the use of TMP combined with advanced innovative technologies and methodologies can pave the way toward large scale realization of organic catalysis.

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“…γ-Al 2 O 3 provided a large number of weak and medium acidic sites. Together with the Ni 3 P hydrogenation center, the bifunctional Ni 3 P/γ-Al 2 O 3 obtained a 74.6% yield of CPO from furfural ( Table 2 , Entry 27) [ 79 ]. Triple-functional Sr 2 P 2 O 7 /Ni 2 P was synthesized by a one-pot hydrothermal synthesis method.…”

Section: Production Of Cpo From Furfuralmentioning

confidence: 99%

A Comprehensive Review on Metal Catalysts for the Production of Cyclopentanone Derivatives from Furfural and HMF

Duan

Cheng

et al. 2023

Molecules

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The catalytic transformation of biomass-based furan compounds (furfural and HMF) for the synthesis of organic chemicals is one of the important ways to utilize renewable biomass resources. Among the numerous high-value products, cyclopentanone derivatives are a kind of valuable compound obtained by the hydrogenation rearrangement of furfural and HMF in the aqueous phase of metal–hydrogen catalysis. Following the vast application of cyclopentanone derivatives, this reaction has attracted wide attention since its discovery, and a large number of catalytic systems have been reported to be effective in this transformation. Among them, the design and synthesis of metal catalysts are at the core of the reaction. This review briefly introduces the application of cyclopentanone derivatives, the transformation mechanism, and the pathway of biomass-based furan compounds for the synthesis of cyclopentanone derivatives. The important progress of metal catalysts in the reaction since the first report in 2012 up to now is emphasized, the characteristics and catalytic performance of different metal catalysts are introduced, and the critical role of metal catalysts in the reaction is discussed. Finally, the future development of this transformation process was prospected.

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Highly selective hydrogenative ring-rearrangement of furfural to cyclopentanone over a bifunctional Ni3P/γ-Al2O3 catalyst

Cited by 5 publications

References 50 publications

Effect of nano-Al₂O₃ and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Effect of nano-Al₂O₃ and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

A Comprehensive Review on Metal Catalysts for the Production of Cyclopentanone Derivatives from Furfural and HMF

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Highly selective hydrogenative ring-rearrangement of furfural to cyclopentanone over a bifunctional Ni3P/γ-Al2O3 catalyst

Cited by 5 publications

References 50 publications

Effect of nano-Al2O3 and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Effect of nano-Al2O3 and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Transition Metal Phosphide Nanoarchitectonics for Versatile Organic Catalysis

A Comprehensive Review on Metal Catalysts for the Production of Cyclopentanone Derivatives from Furfural and HMF

Contact Info

Product

Resources

About

Effect of nano-Al₂O₃ and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge

Effect of nano-Al₂O₃ and multi-walled carbon nanotubes on the anaerobic mono-digestion of sludge and the co-digestion of tobacco waste and sludge