Highly selective electrochemical fluorination of organic compounds in ionic liquids

Electrochemical fluorination of dimethyl glutarate and its characterization

“…These studies indicate high selectivity toward fluorination of active methylene group attached to sulfur atom [5][6][7][8].…”

“…Partial fluorination of aromatic compounds by electrochemical method in fluoride containing solvent-free electrolyte systems has been extensively studied and reviewed [5][6][7][8].…”

A comparative study of anodic fluorination of N-alkyl and N,N-dialkyl phenylacetamides in Et3N·4HF medium

“…Chemical fluorination can also be achieved by using halide exchange process [19] or by employing other novel fluorinating agents [20]. Solvent free Et 3 N Á nHF and Et 4 NF Á mHF has been successfully employed for anodic fluorination of compounds which are more difficult to fluorinate in presence of solvents [21,23,[25][26][27][28][29].…”

Ionic liquids: a versatile medium for palladium-catalyzed reactions

“…ILs have made significant progress in recent years in the catalytic processes. [14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30] They are liquid salts in which the ions are poorly coordinated. ILs are not simply salts dissolved in liquid but they usually exist as liquid below 100 °C, or even at room temperature (room temperature ionic liquids; RTILs).…”