“…Atom-economic catalytic addition reactions of various heteroatom-hydrogen (E-H) bonds to unsaturated substrates have enriched the field of organic synthesis by introducing a number of powerful synthetic approaches. 1 Using transition metal catalysis, various highly efficient catalytic systems leading to stereo-and regioselective carbon-heteroatom bond construction have been developed for C-Si, 2 C-S, [3][4][5][6] C-P, [7][8][9] C-Se, 4,10 C-N, 11,12 C-O, 11,13 C-I, 14,15 and other C-E bonds formation.…”