Highly Selective Carbon Dioxide Capture and Cooperative Catalysis of a Water‐Stable Acylamide‐Functionalized Metal–Organic Framework

Wang, Zhaoxu; Luo, Xin; Zheng, Baishu; Huang, Lu; Cheng, Hui‐Ming; Jiao, Yinchun; Cao, Xiyang; Zeng, Wenjiang; Yun, Ruirui

doi:10.1002/ejic.201701404

Cited by 31 publications

(14 citation statements)

References 69 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The NMR analysis data clearly revealed that the pure product (ethyl 6-methyl-2-oxo-4-phenyl-3,4-dihydro-1H-pyrimidine-5-carboxylate) could be synthesised from benzaldehyde, ethyl acetoacetate and urea using the coordination polymers as reaction catalysts. The spectral data of the obtained Biginelli product (ethyl 6-methyl-2-oxo-4-phenyl-3,4-dihydro-1H-pyrimidine-5-carboxylate) are the following: 1 The yields of the products of heterogeneous catalysis using the synthesised hybrid organic-inorganic compounds are displayed in 3 •DMF agglomerates showed an evident tendency of transformation to hexagonic crystallites. Therefore, we can conclude that the catalytic activity of the synthesised hybrid organic-inorganic compounds was very dependent on the surface microstructure of these hybrid materials.…”

Section: Resultsmentioning

confidence: 99%

“…The assembly of multifunctional ligands with metal ions is currently of great interest due to their use in constructing two-and three-dimensional polymers with special properties, such as electrical conductivity, magnetism, host-guest chemistry, catalysis and luminescence [1][2][3][4]. Reactions of Me x+ NO 3 • yH 2 O (Me x+ = Fe 3+ , Ni 2+ , Mn 2+ , Co 2+ ) with respectively 4-nitrosalycilic (4NSA) and acids [5] produced hybrid organic-inorganic compounds.…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Solvothermally derived Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF: Application as Biginelli reaction catalysts

Laurikenas¹,

Yalçın²,

Žilinskas³

et al. 2019

chemija

View full text Add to dashboard Cite

The solvothermal synthesis between Me(NO3)x ∙ yH2O (Mex+ = Fe3+, Ni2+, Mn2+, Co2+, Cu2+) and respectively 4-nitrosalycilic (4NSA) and 5-sulfosalicylic (5SSA) acids produced hybrid organic-inorganic compounds composed of Mex+ ions and organic fragments which include three different functional groups, carboxylic, hydroxyl and sulfonic, each coordinated to the Mex+ ions. The phase and chemical composition, microstructure and properties of Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF (DMF – dimethylformamide) hybrid compounds were evaluated and discussed. The synthesised materials were characterised by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM) and nuclear magnetic resonance (NMR) spectroscopy. The catalytic properties of the obtained compounds were also investigated.

show abstract

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Solvothermally derived Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF: Application as Biginelli reaction catalysts

Laurikenas¹,

Yalçın²,

Žilinskas³

et al. 2019

chemija

View full text Add to dashboard Cite

show abstract

“…Natural gas distributed energy systems produce almost no solid waste, which eases the burden of urban waste treatment. Water pollution caused by electricity reached about 2 billion cubic meters [52]. Several worldwide environmental conferences mentioned worsening situations of water pollution.…”

Section: Strengthsmentioning

confidence: 99%

Towards a sustainable distributed energy system in China: decision-making for strategies and policy implications

et al. 2019

View full text Add to dashboard Cite

Background: The conflict between the Chinese fossil fuel-based economy and worsening environmental conditions requires further research to be carried out. Due to their clean, highly-efficient and flexible properties, distributed energy systems (DESs) have become a global research focus in the field of energy conservation. China, as the largest coal-fired energy user and highest power consumer in the world, has to conduct further research and apply the DESs to resolve the conflict. This study aims to provide a comprehensive review of DES development in China as well as improvement suggestions for the development of DESs by use of scientific analysis. Methods: The analysis of strengths-weaknesses-opportunities threats (SWOT) was adapted for the analysis of improvement strategies. The directions for how to improve the application of these strategies were selected by the prioritization method of analytic hierarchy processes (AHP) and evaluated by the best-worst method (BWM). The suggestions were provided according to the ranks figured out by AHP and BWM. Five enablers were selected from the respective economic, environmental, technological and social aspects for participating in this analysis. Results: Resulting from the SWOT analysis, capital investment, technology development and regulation completeness are three aspects of strategies summarized as SO strategies, ST strategies, WO strategies and WT strategies. The research perspectives of DESs that are suggested for investment, technology development and regulation completeness are illustrated by AHP and BWM. The results show that the reduction of solid particle emissions, the improvement of generation reliability, the improvement of the production rate, the reduction of production costs, the improvement of on-site safety, the fulfilment of electricity demand, the reduction of noxious gas emissions as well as the improvement of energy efficiency need to be carried out for the sake of environmental protection and quality of DES generation in China.Conclusions: There are high potentials for China to further develop and apply DES approaches. The direction of current development might be set to solve three problematic aspects, which are capital investment, technology development and regulation completeness.

show abstract

“…In the past two decades, enormous progress has been made in the synthesis and application of MOFs [3,4,5]. Because of their remarkable structural features, such as high porosity and large surface area, as well as their exceptional physicochemical properties, MOFs possess versatile applications in gas storage and separation [6,7,8,9,10,11], heterogeneous catalysis [12,13,14,15], drug delivery and chemotherapy [16,17], and sensing [18,19]. As new types of promising functional materials, luminescent MOFs especially have great potential as alternative phosphors in lighting devices and luminescent sensors [20,21,22,23].…”

Section: Introductionmentioning

confidence: 99%

Recent Progress in Metal–Organic Framework (MOF) Based Luminescent Chemodosimeters

et al. 2019

View full text Add to dashboard Cite

Metal–organic frameworks (MOFs), as a class of crystalline hybrid architectures, consist of metal ions and organic ligands and have displayed great potential in luminescent sensing applications due to their tunable structures and unique photophysical properties. Until now, many studies have been reported on the development of MOF-based luminescent sensors, which can be classified into two major categories: MOF chemosensors based on reversible host–guest interactions and MOF chemodosimeters based on the irreversible reactions between targets with a probe. In this review, we summarize the recently developed luminescent MOF-based chemodosimeters for various analytes, including H2S, HClO, biothiols, fluoride ions, redox-active biomolecules, Hg2+, and CN−. In addition, some remaining challenges and future perspectives in this area are also discussed.

show abstract

Highly Selective Carbon Dioxide Capture and Cooperative Catalysis of a Water‐Stable Acylamide‐Functionalized Metal–Organic Framework

Cited by 31 publications

References 69 publications

Solvothermally derived Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF: Application as Biginelli reaction catalysts

Solvothermally derived Me2(H2O)4(5SSA)3·DMF and Me2(H2O)4(4NSA)2·DMF: Application as Biginelli reaction catalysts

Towards a sustainable distributed energy system in China: decision-making for strategies and policy implications

Recent Progress in Metal–Organic Framework (MOF) Based Luminescent Chemodosimeters

Contact Info

Product

Resources

About