Highly Selective and Sensitive Detection of PO<sub>4</sub><sup>3–</sup> Ions in Aqueous Solution by a Luminescent Terbium Metal–Organic Framework

Zhao, Shenglu; Xiao, Jiannan; Zheng, Tianxiang; Wu, Haonan; Liu, Zhiliang

doi:10.1021/acsomega.9b01911

Cited by 30 publications

(17 citation statements)

References 53 publications

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“…Comparing to results in the literature obtained by fluorescent sensors shows LOD values very close to those obtained for phosphate, such as 4.5×10 −6 or 4.5 ppm [30] for Tb‐MOF; 4.3×10 −9 mol dm −3 for Eu‐complex based FRET; [31] 2.9×10 −8 mol dm −3 for copper complex [32] and as colorimetric sensors about 3.00×10 −8 mol dm −3 , [8] depicting chemosensor 1 can detect low concentrations of these anions above using the UV‐Vis method and are according to results from the literature.…”

Section: Resultssupporting

confidence: 81%

Selective Aminothiazole‐Derivative Probe for Detection of Phosphate in Freshwater

et al. 2022

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Phosphate anions have been used in agriculture, the food industry, and cleaning products, and their excess causes eutrophication of drinking water and aquatic systems, affecting the entire aquatic ecosystem. This study developed an aminothiazole-derivative selective probe to recognize phosphate, even in high levels of contaminants, through hydrogen donor groups using UV-Vis and NMR spectroscopies to overcome the challenges. Chemosensors 1 depicted high sensibility and selectivity for PO 4 3À anion demonstrated by the UV-Vis; the limit of detection (LOD) for PO 4 3À (2.4 × 10 À 7 mol dm À 3 ) validated it as a chemosensor with low concentrations detection for anions, and 1 was utilized to detect and analyze real water samples with recoveries of 91 % and 109 %. NMR titrations confirmed that the binding mechanism of the chemosensors 1 occurred by hydrogen bonding of the NH amide group with that ion. Chemosensor 1 exhibited a low-cost, easy-to-use, and selective phosphate detection in freshwater, even in high nitrite and nitrate anions concentrations in eutrophic environments.

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Section: Resultssupporting

confidence: 81%

Selective Aminothiazole‐Derivative Probe for Detection of Phosphate in Freshwater

et al. 2022

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“…Phosphorus (P) is referred to as a limiting nutrient in the context of water degradation through eutrophication. Excess P concentration can trigger abnormal growth of aquatic plants, particularly, algae . Many researchers have provided evidence highlighting the acceleration of eutrophication when P concentration exceeds 0.02 mg L –1 .…”

Section: Introductionmentioning

confidence: 99%

Removal of Phosphorus from an Aqueous Solution by Nanocalcium Hydroxide Derived from Waste Bivalve Seashells: Mechanism and Kinetics

Khan

Thannaree

et al. 2020

ACS Omega

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Excessive supply of phosphorus, a vital macronutrient for all organisms, can cause unwanted environmental consequences such as eutrophication. An increase in agricultural and industrial activities has created a considerable imbalance in the phosphorus cycle with continuing adverse effects on sustainability and ecosystem health, thereby stipulating/postulating the significance of phosphorus removal. A unique and sustainable concept for the removal of phosphorus through the utilization of waste bivalve seashells was proposed in the present study. Flat-surfaced and hexagonally shaped nanocalcium hydroxide particles (∼96% purity) with size ranging from 100 to 400 nm have been synthesized, and phosphorus from its aqueous solution is treated via precipitation. An optimization study has been conducted using the Box−Behnken design of response surface methodology, which highlights that with a calcium/phosphorus mass ratio, pH, and temperature of 2.16, 10.20, and 25.48 °C, a phosphorus removal efficiency of 99.33% can be achieved in a residence time of 10 min. Also, under the same conditions, diluted human urine was analyzed and phosphorus removal efficiency of ∼95% was observed. Through experimental results, semiquantitative phase analysis, and transmission electron microscopy, it has been found that the reaction was diffusion-controlled, which was further confirmed through shrinking core diffusion modeling. The present study manifests the promising potential of waste seashell-derived nanocalcium hydroxide for phosphorus treatment and its precipitation in the form of value-added hydroxyapatite.

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“…Zhao et al prepared Tb-MOF based on 5-(1H-pyrazol-3-yl)isophthalic acid (H 2 pia) [146]. Free H 2 pia ligand displayed an emission peak at 393 nm upon excitation at 331 nm.…”

Section: Benzimidazole Derivativesmentioning

confidence: 99%

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

et al. 2020

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Coordination polymers are constructed from metal ions and bridging ligands, linking them into solid-state structures extending in one (1D), two (2D) or three dimensions (3D). Two- and three-dimensional coordination polymers with potential voids are often referred to as metal-organic frameworks (MOFs) or porous coordination polymers. Luminescence is an important property of coordination polymers, often playing a key role in their applications. Photophysical properties of the coordination polymers can be associated with intraligand, metal-centered, guest-centered, metal-to-ligand and ligand-to-metal electron transitions. In recent years, a rapid growth of publications devoted to luminescent or fluorescent coordination polymers can be observed. In this review the use of fluorescent ligands, namely, 4,4′-stilbenedicarboxylic acid, 1,3,4-oxadiazole, thiazole, 2,1,3-benzothiadiazole, terpyridine and carbazole derivatives, naphthalene diimides, 4,4′,4′′-nitrilotribenzoic acid, ruthenium(II) and iridium(III) complexes, boron-dipyrromethene (BODIPY) derivatives, porphyrins, for the construction of coordination polymers are surveyed. Applications of such coordination polymers based on their photophysical properties will be discussed. The review covers the literature published before April 2020.

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Highly Selective and Sensitive Detection of PO₄^3– Ions in Aqueous Solution by a Luminescent Terbium Metal–Organic Framework

Cited by 30 publications

References 53 publications

Selective Aminothiazole‐Derivative Probe for Detection of Phosphate in Freshwater

Selective Aminothiazole‐Derivative Probe for Detection of Phosphate in Freshwater

Removal of Phosphorus from an Aqueous Solution by Nanocalcium Hydroxide Derived from Waste Bivalve Seashells: Mechanism and Kinetics

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

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Highly Selective and Sensitive Detection of PO43– Ions in Aqueous Solution by a Luminescent Terbium Metal–Organic Framework

Cited by 30 publications

References 53 publications

Selective Aminothiazole‐Derivative Probe for Detection of Phosphate in Freshwater

Selective Aminothiazole‐Derivative Probe for Detection of Phosphate in Freshwater

Removal of Phosphorus from an Aqueous Solution by Nanocalcium Hydroxide Derived from Waste Bivalve Seashells: Mechanism and Kinetics

Coordination Polymers Based on Highly Emissive Ligands: Synthesis and Functional Properties

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Highly Selective and Sensitive Detection of PO₄^3– Ions in Aqueous Solution by a Luminescent Terbium Metal–Organic Framework