Highly Reactive π-Arene Iron Complexes and their use in Stoichiometric and Catalytic Cyclic Addition Reactions

In 1969, P. L. Timms reported the first preparative cocondensation reactions of metal vapors with organic and inorganic substrates. The use of this technique in preparative chemistry soon spread rapidly, but in recent years there has been less activity in this sector. If metal atom reactions are not utilized primarily for the formation of new products, but for the synthesis of highly reactive intermediates, a new synthetic strategy may be developed. Our aims are reaction sequences which, based on an effective cocondensation reaction, lead gradually and selectively to new substance classes. This principle can be illustrated by the example of the cocondensation products of arenes and iron, cobalt, or nickel vapor, which decompose between -70 and -50°C. The classes of products accessible by this method extend from clusters, through x-complexes, organophosphorus and organoboron cage compounds to pure organic cycloaddition products.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Highly Reactive π-Arene Iron Complexes and their use in Stoichiometric and Catalytic Cyclic Addition Reactions

Cited by 2 publications

References 30 publications

Hochreaktive Zwischenverbindungen aus Cokondensationsreaktionen von Eisen‐, Cobalt‐ und Nickeldämpfen mit Arenen

Hochreaktive Zwischenverbindungen aus Cokondensationsreaktionen von Eisen‐, Cobalt‐ und Nickeldämpfen mit Arenen

Highly Reactive Intermediates from the Cocondensation Reactions of Iron, Cobalt and Nickel Vapor with Arenes

Contact Info

Product

Resources

About