Highly Performance Core-Shell TiO2(B)/anatase Homojunction Nanobelts with Active Cobalt phosphide Cocatalyst for Hydrogen Production

Abstract

In this paper, a highly efficient core-shell structure of TiO2(B)/anatase photocatalyst with CoP cocatalyst has been synthesized via hydrothermal processes and a mechanical milling method. The designed core-shell TiO2(B)/anatase photocatalysts exhibit excellent performance by compared with pure TiO2(B) and anatase phase. With the participation of CoP particles, there is drastically enhanced photocatalytic activity of TiO2(B)/anatase, and the H2-production rate can be up to 7400 μmol·g−1, which is about 3.2 times higher than TiO2(B)/anatase photocatalyst. The improved activity is attributed to the contribution of the well-matched core-shell structure and cooperative effect of CoP cocatalyst. The photogenerated holes of anatase can migrate more promptly to the adjacent TiO2(B) core than the photogenerated electrons, which result in an accumulation of electrons in the anatase, and CoP nanoparticles can contribute significantly to transferring electrons from the surface of TiO2(A). It was found that the efficient separation of electron-hole pairs greatly improved the photocatalytic hydrogen evolution in water under UV light irradiation.

Controlling interface properties for enhanced photocatalytic performance: a case-study of CuO/TiO2 nanobelts

“…Obviously, the nude TiO 2 nanobelts display the characteristic diffraction peaks of TiO 2 . 34 Similarly, the CuO/ TiO 2 nanobelts with different CuO contents also exhibit the characteristic diffraction peaks of TiO 2 . However, new diffraction peaks appear at 35.51 and 38.71, which are assigned to the (002) and (111) crystal planes of cubic CuO (JCPDS 45-0937), 35 as shown in Fig.…”

A New Functional Composite for Photovoltaic and Sensor Applications

“…Both transferred electrons from anatase TiO 2 and electrons directly excited to the CB of the titanate phase can supply more free electrons to FTO resulting in a better performance. [ 48–50 ]…”

Photocatalytic degradation and mineralization of dye pollutants from wastewater under visible light using synthetic CuO-VO2/TiO2 nanotubes/nanosheets

“…However, the corresponding values for CuO-VO 2 , a p-type semiconductor, are ? 0.1 and 2.96 eV, respectively, according to the Mott-Schottky analysis [79]. The presence of CuO and VO 2 in the nanocomposite decreases the band gap to 2.5 eV, which is appropriate for the absorbance of visible light in photcatalytic reactions (Fig.…”

“…The photoexcited charge carriers are capable of recombination and participation in the photocatalytic reaction [77,78]. The conduction and valence band edge values of TiO 2 , an n-type semiconductor, are 3.2 and -0.1 eV, respectively [79]. However, the corresponding values for CuO-VO 2 , a p-type semiconductor, are ?…”