An ultrasonic mist pyrolysis system has been used to fabricate thick films of YBa2Cu30,., (YBCO) on rolled and single crystal silver substrates. The substrates were heated .to 900°C and nitrate solutions of the constituent cations were sprayed using a nitrogen carrier gas. Highly c-axis aligned YBCO films were obtained by deposition at a rate of -1pm per minute. Phase pure YBCO formed up to a limit of -6pm. For thicker films, BaCuO, and Y2BaCu05 also formed. On (110) oriented single crystal silver, the films showed in-plane alignment with a four fold symmetry, and the FWHM in the azimuthal direction of the main peaks was -3". On the polycrystalline substrate the in-plane texture showed a -20" FWHM, equivalent to that of the (110)<110> textured silver substrate. The onset of the superconducting transition was measured as -90.2"C for a sample with a film thickness of -5pm.