Abstract:Chapter 1 introduces the traditional organic chemistry of pyridine with an emphasis on its dearomatization. Organometallic methods of dearomatization are also discussed. Strategies for averting nitrogen coordination (i.e. κN) in favor of haptotropic (i.e. η 2 , η 4 , η 6 ) pyridine coordination are discussed, as well as known modifications of these carbon-coordinated pyridines. The work previously performed by our group with {TpW(NO)(PMe 3 )} and our strategy to utilize this fragment is introduced.Chapters 2 a… Show more
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