Highly Flexible and Reversible Stimuli‐Responsive Photonic Crystal Film in Anti‐Counterfeit, Detector, and Coating

Abstract

Various fascinating optical characteristics in organisms encourage scientists to develop biomimetic synthesis strategies and mimic their unique microstructure. Inspired by the Chameleon's skin with tunable color and superior flexibility, this work designs the evaporated‐induced self‐assembly technique to synthesize the chiral photonic crystal film. Ultrasonic‐intensified and additive‐assisted techniques synergistically optimize the film properties, on the aspects of optic and mechanic. The film shows considerable rigidity and superior flexibility, which can undergo multiple mechanical deformations. Without destroying the chiral nematic structure, the ultimate strain approaches 50%, which exceeds most cellulose‐derived film materials. It also integrates excellent optical performance. The film color can cover the total visible region by tuning the photonic bandgap and has angle‐dependent properties. It can make the response to humidity and solvents, and chromaticity variation reflects the degree of stimulation. Importantly, this structural‐dependent color change is reversible. Lastly, the photonic crystal materials with excellent mechanics and unique optics have been applied in the security. The anti‐counterfeiting material design contains photonic crystal ink, repeatable writing paper, information‐hiding film, and color‐changing labels, with the features of environmentally friendly, economical, non‐destructive, and convenient for authentication.