“…Contrary to (E)-b,b-disubstituted a,b-unsaturated esters, members of the (Z)-configured cohort have proven very hard to hydrogenate with excellent ee by using N,P-chelated iridium catalysts. [20] We found the hydrogenation of substrate 11 by [(A)*IrA C H T U N G T R E N N U N G (cod)] + A C H T U N G T R E N N U N G [BAr F ] À to be no exception, as an Table 1. Asymmetric hydrogenation of (E)-b,b-disubstituted a,b-unsaturated esters.…”