“…Traditional noble metal catalysts (e.g., Pt, Rh, and Ir and their oxides) , are too expensive for large-scale applications . To lower the cost, earth-abundant transition-metal-based compounds have been explored extensively. − Among different materials, polyoxometalate (POM) compounds exhibit a wide variety of elemental compositions and versatile molecular structures, leading to their interesting physical and chemical properties. ,,− Among many types of POMs, the Wells–Dawson type, with the general formula [X 2 M 18 O 62 ] n − , has been widely exploited for PC water splitting reactions because of their ease of synthesis and unique chemical/electron-transfer properties. For example, Duan and co-workers have reported a variety of Wells–Dawson-type POMs embedded in the pores of REDOX-active coordination polymers or other material matrixes for PC hydrogen evolution. , They have shown that the Dawson-type P 2 W 18 polyanion plays a key role in affecting the rate of hydrogen evolution by synergistically interacting with other substances.…”