Highly Efficient Thiolate‐Based Ionic Liquid Catalysts for Reduction of CO2: Selective N‐Functionalization of Amines to Form N‐Formamides and N‐Methylamines
Jiakai Wu,
Junping Niu,
Lu Hou
et al.
Abstract:Developing efficient catalysts to convert CO2 into value‐added chemicals is valuable for reducing carbon emissions. Herein, a kind of novel thiolate‐based ionic liquid with sulfur as the active site was designed and synthesized, which served as highly efficient catalyst for the reductive functionalization of CO2 by amines and hydrosilane. By adjusting the CO2 pressure, various formamides and methylamines were selectively obtained in high yields. Remarkably, at the catalyst loading of 0.1 mol%, the N‐formylatio… Show more
Thiolate-based ionic liquids, specifically the catalyst [TBP][2-Tp], have demonstrated their efficiency in catalyzing the reaction of CO2 with propargylic amine. This novel synthetic method can be used to synthesize various...
Thiolate-based ionic liquids, specifically the catalyst [TBP][2-Tp], have demonstrated their efficiency in catalyzing the reaction of CO2 with propargylic amine. This novel synthetic method can be used to synthesize various...
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