Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Platinum and Palladium Aryl Oxime Metallacycles

Cyclometalated N,N-dimethylbenzylamine ruthenium(II) complexes [Ru(C6HR1R2R3-o-CH2NMe2)(bpy)(RCN)2]PF6 for bioapplications: synthesis, characterization, crystal structures, redox properties, and reactivity toward PQQ-dependent glucose dehydrogenase

“…The most impressive progress has been achieved in fine organic synthesis [2][3][4][5], metalcomplex [6][7][8][9] and biochemically inspired catalysis [10,11]. Recently, we have disclosed a new sphere for using cyclometalated ruthenium and osmium compounds.…”

Mononuclear versus dinuclear palladacycles derived from 1,3-bis(N,N-dimethylaminomethyl)benzene: Structures and catalytic activity

“…Since their widespread use and persistence, the environmental accumulation of these toxic chemicals present an ecological and health threat. It has been noticed that C,N-ortho cyclometalated palladium and platinium complexes can effectively catalyze the hydrolysis of these materials [11][12][13]. We have reported before that a palladated complex with N,N-dimethylaminomethylphenyl ligand, namely Pd(dmba)(py)(OTf), promotes the methanolysis of phosphorothionates, demonstrating great catalytic efficacy and specificity toward these P=S derivatives [14].…”

Synthesis, structures and catalytic properties of palladacycles derived from N,N-dimethylaminomethylferrocene

“…t 1/2 values of less than a few minutes. Recently it was shown that some C,N-ortho cyclometalated palladium and platinium complexes can effectively catalyze the hydrolysis of phosphorothionates [7][8][9][10]. More recently, we have shown that a palladated complex containing the N,N-dimethylaminomethylphenyl ligand, namely Pd(dmba)-(py)(OTf), also promotes the methanolysis of phosphorothionates and shows greater catalytic efficacy in terms of reaction rate relative to the hydrolytic process [11].…”