Hydrogen-based energy systems hold promise for sustainable
development
and carbon neutrality, minimizing environmental impact with electrolysis
as the preferred fossil-fuel-free hydrogen generation method. Effective
electrocatalysts are required to reduce energy consumption and improve
kinetics, given the need for additional voltage (overpotential, η)
despite the theoretical water splitting potential of 1.23 V. To date,
platinum has been acknowledged as the most effective but expensive
hydrogen evolution reaction (HER) catalyst. Hence, we introduce a
cost-effective (∼2-fold cheaper) ruthenium-modified tungsten
diphosphide (Ru/WP2) catalyst on carbon fiber for HER in
∼0.5 M H2SO4, with η ≈ 34
mV at −10 mA cm–2 which can be comparable
(only ∼2-fold higher) to benchmark Pt/C (η ≈ 17
mV). The HER performance of WP2 can be enhanced through
the modification of ruthenium, as indicated by the electrochemical
characterizations. Considering the Tafel value of ∼40 ±
0.2 mV dec–1, it can be inferred that Ru/WP2 follows the Volmer–Heyrovsky reaction pathway for
hydrogen generation. Furthermore, the Faradaic efficiency estimation
indicates that Ru/WP2 demonstrates a minimal loss of electrons
during the electrochemical reaction with an estimated value of ∼98.7
± 1.4%. Therefore, this study could emphasize the potential of
the Ru/WP2 electrode in advancing sustainable hydrogen
production through water splitting.