2015
DOI: 10.1039/c5tc00276a
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Highly conductive PEDOT:PSS films by post-treatment with dimethyl sulfoxide for ITO-free liquid crystal display

Abstract: In this study, a simple and effective method to enhance the conductivity of poly(3,4-ethylenedioxythiphene):poly(styrenesulfonate) (PEDOT:PSS) thin films from 0.7 to 1185 S cm À1 by post-treatment with dimethyl sulfoxide (DMSO) is demonstrated. After the rubbing technique was applied, the DMSO-treated PEDOT:PSS film could be used as both the transparent electrode and the alignment layer to fabricate ITO-free liquid crystal (LC) cells. The electro-optical properties of LC cells fabricated by the rubbed PEDOT:PS… Show more

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Cited by 158 publications
(103 citation statements)
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“…1d). Nonetheless, this metric is still very high in comparison with the other values reported in the literature [37][38][39] . Therefore, the robustness of the highly crystalline fibrillar nanostructures is responsible for the long-term electrical, optical, and mechanical stabilities of c-PEDOT:PSS in aqueous, ionic environments 34 .…”
Section: Resultsmentioning
confidence: 47%
“…1d). Nonetheless, this metric is still very high in comparison with the other values reported in the literature [37][38][39] . Therefore, the robustness of the highly crystalline fibrillar nanostructures is responsible for the long-term electrical, optical, and mechanical stabilities of c-PEDOT:PSS in aqueous, ionic environments 34 .…”
Section: Resultsmentioning
confidence: 47%
“…where A is the absorbance, 3 is the absorption coefficient, b is the distance that light travels through the material (the path length), and c is the concentration of the absorbing species in the material. Since the absorbance of PEDOT:PSS at 550 nm is predominantly affected by PEDOT, 28 the change in the concentration of PEDOT:PSS together with the time taken for absorbance can be thought of as the amount of EDOT used in the polymerization process. 29,30 As a result, the EDOT-to-PEDOT polymerization rate can be calculated using UV-Vis-NIR data.…”
Section: Resultsmentioning
confidence: 99%
“…The binary nanocomposite coating gives lower electrical resistivity than ternary epoxy‐blended nanocomposite coating. This is probably due to the fact that PEDOT:PSS is a conductive polymer (resistivity down to 10 −3 Ω cm) while the insulating epoxy resin increases the overall resistivity of the coating. The insulating epoxy might be also placed between conductive fillers and leads to an increase of the fillers' contact resistance.…”
Section: Resultsmentioning
confidence: 99%