Highly conducting linear stacked polymers: iodine-doped fluoroaluminum and fluorogallium phthalocyanines

Nohr, Ronald S.; Kuznesof, Paul M.; Wynne, Kenneth J.; Kenney, Malcolm E.; Siebenman, P. G.

doi:10.1021/ja00405a014

Cited by 123 publications

(28 citation statements)

References 1 publication

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“…12 and the unit cell parameters are as follows: tetragonal; space group P4 2 /n; a = 21.676 (8), c = 7.474(4) Å ; V = 3511(3) Å 3 ; Z = 2. The Pc units form a one-dimensional chain with type A overlaps along the c-axis.…”

Section: Tpp[co(pc)(cn) 2 ]mentioning

confidence: 99%

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Novel phthalocyanine‐based conductors: tunable Π–Π stacking structure through the steric and chemical interactions of axial ligands

Inabe

2001

J. Porphyrins Phthalocyanines

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Section: Tpp[co(pc)(cn) 2 ]mentioning

confidence: 99%

“…Li(Pc) and Lu(Pc) 2 [6], and many polymeric conductors, e.g. {[M(Pc)O]X y } n (MSi, Ge [7]), {[M(Pc) F]X y } n (MAl, Ga [8]) and [M(Pc)Z] n (MFe, Co, etc. ; ZCN, pyrazine, etc.…”

Section: Introductionmentioning

confidence: 99%

Novel phthalocyanine‐based conductors: tunable Π–Π stacking structure through the steric and chemical interactions of axial ligands

Inabe

2001

J. Porphyrins Phthalocyanines

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“…It is known that the precursors with different structure can result in different kinds of polymeric phthalocyanines. 10 Cofacial polymeric phthalocyanines, such as polysiloxane 11,12 and poly aluminum phthalocyanine, 13 are prepared from reactions involving the axial ligands attached to ions residing in the central cavity. Their phthalocyanine rings only extend in their axial direction as linear form.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, characterization and electrical properties of novel steric phthalocyanine polymers

et al. 2010

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Two novel steric polymeric phthalocyanines, with copper (CuPPc) and aluminum hybrid zinc (Al/ZnPPc) as the central atoms, were synthesized by the cyclic condensation of tetrahedral tetra-phthalonitriles. The IR and UV-VIS spectra of the synthesized polymers indicated a moderate degree of polymerization, somewhere between the monomeric phthalocyanine and planar covalent polymer. Good thermal stability and a high metallic content of CuPPc and Al/ZnPPc were verified by TGA and ICA-AAS methods. The metallic atoms were distributed uniformly and exhibited different binding features with -CN, -O, -N in the polymer, as indicated by EDS and XPS analysis. High electrical conductivity was observed before and after iodine doping compared to the normal polymeric phthalocyanine.

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“…catalytic, electrocatalytic, electrochemical and photochemical activities [1][2][3]. Synthesis and structure of the polymer were studied in detail for the reaction of 1,2,4,5-benzenetetracarbonitrile with various metal salts or metals [4][5][6][7][8][9].…”

Section: Introductionmentioning

confidence: 99%

Tetrathia Macrocycle-bridged Dimeric with Hexakis (alkylthio) Substituents and Network Polymer Phthalocyanines

Gürek¹,

Ğlu

1997

J. Porphyrins Phthalocyanines

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1,4,7,10-Tetrathia (12-crown-4)-bridged new polymeric phthalocyanines 9 and 10 have been synthesized by the reaction of tetracyanodibenzo[1,4,7,10-tetrathia (12-crown-4)] in the presence of a strong organic base or Zn ( OAc )2 respectively. Furthermore, 1,4,7,10-tetrathia (12-crown-4)-linked peripherally octa-substituted dimeric phthalocyanine 12, which contains a combination of hexakis(alkylthia) side chains was synthesized by the reaction of subphthalocyanine 11 with the iminoisoindoline derivative 8. The new compounds have been characterized by elemental analyses, IR, UV/vis, mass, 1 H NMR and 13 C NMR spectroscopy. The thermal stabilities of the compounds were determined by thermogravimetric analysis. The electrical conductivity of the polymeric, 9 and 10, and dimeric phthalocyanines, 12 and 13, are in the semiconductor range; chemical doping with NOBF 4 increases the d.c. conductivity of 10 by a factor of four.

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Highly conducting linear stacked polymers: iodine-doped fluoroaluminum and fluorogallium phthalocyanines

Cited by 123 publications

References 1 publication

Novel phthalocyanine‐based conductors: tunable Π–Π stacking structure through the steric and chemical interactions of axial ligands

Novel phthalocyanine‐based conductors: tunable Π–Π stacking structure through the steric and chemical interactions of axial ligands

Synthesis, characterization and electrical properties of novel steric phthalocyanine polymers

Tetrathia Macrocycle-bridged Dimeric with Hexakis (alkylthio) Substituents and Network Polymer Phthalocyanines

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