Highly conducting ionic liquids based on l-ethyl-3-methylimidazolium cation

Yoshida, Yukihiro; Fujii, Junichi; Muroi, K.; Otsuka, Akihiro; Saito, Gunzi; Takahashi, Masahide; Yoko, Toshinobu

doi:10.1016/j.synthmet.2005.07.321

Cited by 50 publications

(32 citation statements)

References 17 publications

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“…The obtained values for the viscosities of the neat RTILs were clearly underestimating literature data [16,17,18,19,20,21,22] [19,20,21,22] scattered considerably and were only partly determined at 25…”

Section: Densities Conductivities and Viscositiescontrasting

confidence: 81%

How ideal are binary mixtures of room-temperature ionic liquids?

Stoppa

Buchner

Hefter

2010

Journal of Molecular Liquids

119

124

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Data for the densities, conductivities, viscosities and dielectric properties of binary mixtures of the tetrafluoroborate and the dicyanamide salts of 1-N-ethyl-3-N-methylimidazolium have been measured at 25• C. The mixtures exhibit practically "ideal" (linear) mixing behaviour with respect to viscosity, molar volume, and the effective dipole moment of the observed relaxation associated with cation reorientation, indicating a smooth change in the structure of the mixtures. On the other hand, the electrical conductivity and dielectric relaxation time deviate considerably from "ideal" mixing behaviour, indicating enhanced translational and rotational dynamics in the mixtures.

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Section: Densities Conductivities and Viscositiescontrasting

confidence: 81%

How ideal are binary mixtures of room-temperature ionic liquids?

Stoppa

Buchner

Hefter

2010

Journal of Molecular Liquids

119

124

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show abstract

“…128). 854,855,883 2) it is wholly reasonable that the paramagnetic material is attracted to a magnet regardless of its form (more than 150 years ago, Faraday classified materials into either diamagnetic (repeled by magnet) or paramagnetic (attracted by magnet) ones 885 ) and 3) the physical and chemical characterizations concerning the purity of the ionic liquid are hardly presented in their paper (Table 29), though the purities are critical for molecular magnets.…”

Section: Paramagnetic Ionic Liquidsmentioning

confidence: 99%

Development of Conductive Organic Molecular Assemblies: Organic Metals, Superconductors, and Exotic Functional Materials

Saito¹,

Yoshida²

2007

Bulletin of the Chemical Society of Japan

367

126

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“…In recent years, magnetic ionic liquid [19][20][21] (iron(III) chloride with 1-butyl-3-methylimidazolium chloride) was discovered as a key material for ''green chemistry''. The unique physical and chemical properties of magnetic ionic liquids are strong response to magnetic field [21], paramagnets at room temperature [21,22], possible local ordering of the magnetic anions [21], characteristic phase behavior and electrochemical properties [23], high conductivity [24], and effective catalytic properties [25]. With this expectation in mind, we have prepared new photo-controllable supramolecular system containing magnetic ionic liquid (iron(III) chloride with 1-butyl-3-methylimidazolium chloride) and azobenzene (1) (Fig.…”

mentioning

confidence: 99%