Highly active and stable Co (Co3O4)_Sm2O3nano-crystallites derived from Sm2Co7and SmCo5intermetallic compounds in NH3synthesis and CO2conversion

Marakatti, Vijaykumar S.; Ronda‐Lloret, Maria; Krajčı́, M.; Joseph, Boby; Marini, Carlo; Delgado, Juan J.; Devred, François; Shiju, Raveendran N.; Gaigneaux, Éric M.

doi:10.1039/d1cy01956b

Catal. Sci. Technol.

2022

DOI: 10.1039/d1cy01956b

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Highly active and stable Co (Co₃O₄)_Sm₂O₃nano-crystallites derived from Sm₂Co₇and SmCo₅intermetallic compounds in NH₃synthesis and CO₂conversion

Vijaykumar S. Marakatti¹,

Maria Ronda‐Lloret²,

M. Krajčı́³

et al.

Abstract: Intermetallic compounds (IMCs) are interesting materials in the field of heterogeneous catalysis due to their ordered structure and tunable electronic properties. These IMCs can act as precursor to synthesize metal/metal...

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Bioinspired Catalysis with Biomimetic Clusters

Banerjee,

Paul,

Marakatti

2024

Bioderived Materials: Harnessing Nature for Advanced Biochemical Handiwork

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Biomimetic clusters dubbed inorganic complexes are the foci of many enzymes that are frequently earmarked for biochemical pathways. Specifically, the biomimetic clusters are made up of transition metal(s) chelated with organic ligands. This book chapter details redox active enzymes for the most fundamental biochemical processes. Bio-inorganic chemists have been synthesizing numerous biomimetic clusters that have the ability not only to mimic the active site structural features but also to mimic their functions. In a similar vein, the fixation of nitrogen into ammonia is akin to the fundamental biological process and thus can be considered a biomimetic biological process. Therefore, novel materials, including electrides, nitrides, hydrides, and basic oxides, have created a niche in facilitating biochemical reaction products. Insights into biomimetic clusters, especially inorganic catalysts’ mimics, new materials facilitating biological chemistries, and their mechanisms will uncover new avenues for small molecule activation, with different catalytic mechanisms yet to be elucidated.

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Bioinspired Catalysis with Biomimetic Clusters

Banerjee,

Paul,

Marakatti

2024

Bioderived Materials: Harnessing Nature for Advanced Biochemical Handiwork

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show abstract

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Highly active and stable Co (Co₃O₄)_Sm₂O₃nano-crystallites derived from Sm₂Co₇and SmCo₅intermetallic compounds in NH₃synthesis and CO₂conversion

Abstract: Intermetallic compounds (IMCs) are interesting materials in the field of heterogeneous catalysis due to their ordered structure and tunable electronic properties. These IMCs can act as precursor to synthesize metal/metal...

Cited by 1 publication

References 56 publications

Bioinspired Catalysis with Biomimetic Clusters

Bioinspired Catalysis with Biomimetic Clusters

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