This paper introduces the notion of n-morphisms between two A∞-algebras, such that 0-morphisms correspond to standard A∞-morphisms and 1-morphisms correspond to A∞homotopies between A∞-morphisms. The set of higher morphisms between two A∞-algebras then defines a simplicial set which has the property of being an algebraic ∞-category. The operadic structure of n − A∞-morphisms is also encoded by new families of polytopes, which we call the n-multiplihedra and which generalize the standard multiplihedra. These are constructed from the standard simplices and multiplihedra by lifting the Alexander-Whitney map to the level of simplices. Rich combinatorics arise in this context, as conveniently described in terms of overlapping partitions. Shifting from the A∞ to the ΩBAs framework, we define the analogous notion of n-morphisms between ΩBAs-algebras, which are again encoded by the n-multiplihedra, endowed with a thinner cell decomposition by stable gauged ribbon tree type. We then realize this higher algebra of A∞ and ΩBAs-algebras in Morse theory. Given two Morse functions f and g, we construct n − ΩBAsmorphisms between their respective Morse cochain complexes endowed with their ΩBAs-algebra structures, by counting perturbed Morse gradient trees associated to an admissible simplex of perturbation data. We moreover show that any inner horn of higher morphisms arising from a count of perturbed Morse gradient trees can always be filled, not only algebraically but also geometrically.