Abstract:The electric discharge across a varistor granule filled air gap under a fast-rising voltage pulse was investigated for surge protection applications. The effects of temperature and pressure on the arc and the electrical conduction were analyzed by the characteristic changes in voltage waveforms triggered by a fast-rising high voltage pulse.In addition to the gap size, experimental results show that competing mechanisms among arc conduction, conduction through the varistor granule network, thermionic emission f… Show more
“…Additional details of FRB behaviors associated with PMN–PT granules and dependences on physical variables (viz., temperature and pressure) may be found in Ref. [10].…”
Section: Resultsmentioning
confidence: 99%
“…Cursory DC resistance measurements have in fact revealed large decreases (>11 GΩ to ∼100 kΩ) in some spark‐gap test fixtures after extensive testing consistent with this type of performance outcome, although microscopic examination of granules was not possible at the time. Experimental results indicate that localized arc breakdown induced granule damage can be alleviated by redistribution from shaking the test fixture which alters granule contact points 10 . Although dielectric stimulated arc breakdown is intrinsically stochastic in nature at ambient pressures (i.e., breakdown pathways vary spatially), this type of damage can lead to irreversible alteration in material electrical properties and, consequently, become unreliable for even passing low voltage signals.…”
Section: Resultsmentioning
confidence: 99%
“…PMN–PT granules were loaded into a single pin test fixture (Figure 1) and subjected to repeated electrical impulses of ∼500 ns in duration and applied voltage greater than 1500 V. Details of the experimental setup and procedure were described in detail elsewhere 10 . Briefly, the single pin fixture consists of two conically shaped insulating parts that hold and center a stainless‐steel pin inside a cylindrical shell from both ends with a 300 μm spark gap 10 . The voltage ramp rate was adjusted by a pulse shaping network to be as close as possible to 10 kV/μs to simulate a fast‐rising surge condition.…”
Section: Methodsmentioning
confidence: 99%
“…Unlike more common and broadly used varistor systems, relatively little is currently known about the ability of PMN–PT and similar dielectric materials to withstand repeated arc discharges and associated energy deposition. Although it is tempting to infer similar damage outcomes as observed in varistors, the manners in which surge currents are diverted in both types of materials are fundamentally different (i.e., nonlinear electric field dependent resistance vs. dielectric stimulated arcing) 10 . Moreover, the common assumption that dielectric stimulated arc breakdown in air pockets is self‐healing has not been thoroughly tested and may be compromised if significant chemical change occurs that reduces large electric field splitting 10 needed to induce arcing or creates permanent conduction path through contacts between granules.…”
Section: Introductionmentioning
confidence: 99%
“…Although it is tempting to infer similar damage outcomes as observed in varistors, the manners in which surge currents are diverted in both types of materials are fundamentally different (i.e., nonlinear electric field dependent resistance vs. dielectric stimulated arcing) 10 . Moreover, the common assumption that dielectric stimulated arc breakdown in air pockets is self‐healing has not been thoroughly tested and may be compromised if significant chemical change occurs that reduces large electric field splitting 10 needed to induce arcing or creates permanent conduction path through contacts between granules. We use a combination of scanning electron microscopy (SEM) and energy‐dispersive spectroscopy (EDS) mapping to characterize the effect of arc discharge on local regions of PMN–PT granules subjected to repeated high voltage electrical impulses.…”
Effective diversion of surge currents is vital to prevent unwanted damage to sensitive electronics. Among the most successful and efficient strategies relies on a dielectric stimulated arc breakdown mechanism with high permittivity ceramic granules in a spark-gap geometry. Although generally regarded as a self-healing process, substantial energy deposition may occur that, over time, diminishes the ability to withstand repeated electrical assaults. We investigate the susceptibility of lead-magnesium-niobate-lead titanate (PMN-PT) granule microstructure and composition changes following many exposures to high voltage impulses resulting in arc breakdown. Scanning electron microscopy and energy-dispersive spectroscopy mapping reveal a broad range of thermal and mechanical defects entailing thermal reduction of constituent PMN-PT metal ions and recasting due to rapid eruption of volatile species. Additionally, evidence of local melting and microcracking are apparent that can have deleterious impact on the proper function of the granules, namely, the ability to concentrate electric fields across air gaps to establish and sustain discharge pathways. We propose that the localized nature of damage and stochasticity associated with the dielectric stimulated breakdown mechanism may allow granules to maintain functionality provided no permanent conduction paths are established.
“…Additional details of FRB behaviors associated with PMN–PT granules and dependences on physical variables (viz., temperature and pressure) may be found in Ref. [10].…”
Section: Resultsmentioning
confidence: 99%
“…Cursory DC resistance measurements have in fact revealed large decreases (>11 GΩ to ∼100 kΩ) in some spark‐gap test fixtures after extensive testing consistent with this type of performance outcome, although microscopic examination of granules was not possible at the time. Experimental results indicate that localized arc breakdown induced granule damage can be alleviated by redistribution from shaking the test fixture which alters granule contact points 10 . Although dielectric stimulated arc breakdown is intrinsically stochastic in nature at ambient pressures (i.e., breakdown pathways vary spatially), this type of damage can lead to irreversible alteration in material electrical properties and, consequently, become unreliable for even passing low voltage signals.…”
Section: Resultsmentioning
confidence: 99%
“…PMN–PT granules were loaded into a single pin test fixture (Figure 1) and subjected to repeated electrical impulses of ∼500 ns in duration and applied voltage greater than 1500 V. Details of the experimental setup and procedure were described in detail elsewhere 10 . Briefly, the single pin fixture consists of two conically shaped insulating parts that hold and center a stainless‐steel pin inside a cylindrical shell from both ends with a 300 μm spark gap 10 . The voltage ramp rate was adjusted by a pulse shaping network to be as close as possible to 10 kV/μs to simulate a fast‐rising surge condition.…”
Section: Methodsmentioning
confidence: 99%
“…Unlike more common and broadly used varistor systems, relatively little is currently known about the ability of PMN–PT and similar dielectric materials to withstand repeated arc discharges and associated energy deposition. Although it is tempting to infer similar damage outcomes as observed in varistors, the manners in which surge currents are diverted in both types of materials are fundamentally different (i.e., nonlinear electric field dependent resistance vs. dielectric stimulated arcing) 10 . Moreover, the common assumption that dielectric stimulated arc breakdown in air pockets is self‐healing has not been thoroughly tested and may be compromised if significant chemical change occurs that reduces large electric field splitting 10 needed to induce arcing or creates permanent conduction path through contacts between granules.…”
Section: Introductionmentioning
confidence: 99%
“…Although it is tempting to infer similar damage outcomes as observed in varistors, the manners in which surge currents are diverted in both types of materials are fundamentally different (i.e., nonlinear electric field dependent resistance vs. dielectric stimulated arcing) 10 . Moreover, the common assumption that dielectric stimulated arc breakdown in air pockets is self‐healing has not been thoroughly tested and may be compromised if significant chemical change occurs that reduces large electric field splitting 10 needed to induce arcing or creates permanent conduction path through contacts between granules. We use a combination of scanning electron microscopy (SEM) and energy‐dispersive spectroscopy (EDS) mapping to characterize the effect of arc discharge on local regions of PMN–PT granules subjected to repeated high voltage electrical impulses.…”
Effective diversion of surge currents is vital to prevent unwanted damage to sensitive electronics. Among the most successful and efficient strategies relies on a dielectric stimulated arc breakdown mechanism with high permittivity ceramic granules in a spark-gap geometry. Although generally regarded as a self-healing process, substantial energy deposition may occur that, over time, diminishes the ability to withstand repeated electrical assaults. We investigate the susceptibility of lead-magnesium-niobate-lead titanate (PMN-PT) granule microstructure and composition changes following many exposures to high voltage impulses resulting in arc breakdown. Scanning electron microscopy and energy-dispersive spectroscopy mapping reveal a broad range of thermal and mechanical defects entailing thermal reduction of constituent PMN-PT metal ions and recasting due to rapid eruption of volatile species. Additionally, evidence of local melting and microcracking are apparent that can have deleterious impact on the proper function of the granules, namely, the ability to concentrate electric fields across air gaps to establish and sustain discharge pathways. We propose that the localized nature of damage and stochasticity associated with the dielectric stimulated breakdown mechanism may allow granules to maintain functionality provided no permanent conduction paths are established.
Lowered power loss and asymmetrically electrical parameters are reported in the DC aging of Co2O3-doped ZnO varistors in this paper. Based on the frequency domain dielectric responses of the pristine and degraded samples, the present study explores the roles of point defects in the aging process via dielectric relaxations and their parameters. It is found that breakdown field increased more in the positive direction than the negative direction. Nonlinearity increased in the positive direction, whereas it decreased in the negative direction, and leakage current density increased more in the negative direction than the positive direction. Given the lowest migration energy of Zinc interstitial (Zni, 0.57 eV) and high oxygen ion conductivity in Bi2O3-rich phase, it is speculated that Zni and adsorbed oxygen (Oad) migrate under DC bias, and then change the defect structure and the double Schottky barrier (DSB) at grain boundaries. As a result, the forward-biased barrier height gradually decreases more than the reverse-biased one.
This article reviews the progress in developing ZnO-V2O5-based metal oxide varistors (MOVs) using powder metallurgy (PM) techniques. The aim is to create new, advanced ceramic materials for MOVs with comparable or superior functional properties to ZnO-Bi2O3 varistors using fewer dopants. The survey emphasizes the importance of a homogeneous microstructure and desirable varistor properties, such as high nonlinearity (α), low leakage current density (JL), high energy absorption capability, reduced power loss, and stability for reliable MOVs. This study investigates the effect of V2O5 and MO additives on the microstructure, electrical and dielectric properties, and aging behavior of ZnO-based varistors. The findings show that MOVs with 0.25–2 mol.% V2O5 and MO additives sintered in air over 800 °C contain a primary phase of ZnO with a hexagonal wurtzite structure and several secondary phases that impact the MOV performance. The MO additives, such as Bi2O3, In2O3, Sb2O3, transition element oxides, and rare earth oxides, act as ZnO grain growth inhibitors and enhance the density, microstructure homogeneity, and nonlinearity. Refinement of the microstructure of MOVs and consolidation under appropriate PM conditions improve their electrical properties (JL ≤ 0.2 mA/cm2, α of 22–153) and stability. The review recommends further developing and investigating large-sized MOVs from the ZnO-V2O5 systems using these techniques.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.