During flight, many silicates (sand, dust, debris, fly ash, etc.) are ingested by an engine. They melt at high operating temperatures on the surface of Thermal barrier coatings (TBCs) to form calcium-magnesium-aluminum-silicate (CMAS) amorphous settling. CMAS erodes TBCs and causes many problems, such as composition segregation, degradation, cracking, and disbanding. As a new generation of TBC candidate materials, rare-earth zirconates (Sm2Zr2O7) have good CMAS resistance properties. The reaction products of Sm2Zr2O7 and CMAS and their subsequent changes were studied by the reaction of Sm2Zr2O7 and excess CMAS at 1350°C. After 1 h of reaction, Sm2Zr2O7 powders were not completely eroded. The reaction products were Sm-apatite and c-ZrO2 solutions. After 4 h of reaction, all Sm2Zr2O7 powders were completely eroded. After 24 h of reaction, Sm-apatite disappeared, and the c-ZrO2 solution remained.