2015
DOI: 10.1016/j.ces.2014.09.034
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High-temperature pressure swing adsorption cycle design for sorption-enhanced water–gas shift

Abstract: Sorption-enhanced water-gas shift (SEWGS): H2 from syngas in single unit operation. SEWGS cycle design based on recently published CO 2 and H 2 O interaction with K-HTC. Adsorption of steam during rinse enhances CO 2 product purity. Cycle consumes significantly less steam than previously reported cycle designs.

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Cited by 77 publications
(56 citation statements)
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References 30 publications
(70 reference statements)
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“…Since the SEWGS unit co-captures H 2 S (van Dijk et al, 2011), the preshift section can be designed as sour or clean shift. Because of the increased operating temperature, steam can be used in the cycle to drive both the CO 2 recovery and purity to >95% (Boon et al, 2015), values higher than obtainable for conventional low-temperature PSA separations (Casas et al, 2013). The development of the SEWGS process aims at minimizing the steam requirement for the CO 2 separation in the PSA cycle.…”
Section: Advanced Adsorption Separation Process (Sewgs)mentioning
confidence: 99%
See 1 more Smart Citation
“…Since the SEWGS unit co-captures H 2 S (van Dijk et al, 2011), the preshift section can be designed as sour or clean shift. Because of the increased operating temperature, steam can be used in the cycle to drive both the CO 2 recovery and purity to >95% (Boon et al, 2015), values higher than obtainable for conventional low-temperature PSA separations (Casas et al, 2013). The development of the SEWGS process aims at minimizing the steam requirement for the CO 2 separation in the PSA cycle.…”
Section: Advanced Adsorption Separation Process (Sewgs)mentioning
confidence: 99%
“…The development of the SEWGS process aims at minimizing the steam requirement for the CO 2 separation in the PSA cycle. Depending on the feed composition, the total steam usage in SEWGS is between 0.2 and 2 mol steam per mol CO 2 captured (Boon et al, 2015). Moreover, a significant amount of the steam present in the syngas goes with the high pressure H 2 -rich stream and is used in the combined cycle.…”
Section: Advanced Adsorption Separation Process (Sewgs)mentioning
confidence: 99%
“…To inhibit coke deposition on the catalyst and achieve a purified H 2 output, the process operation is adjusted to 3.5 MPa pressure, steam-to-carbon ratios of 3.5, and high temperatures [42]. After the reformer, the mixture of gases goes through a heat recovery, and water gas shift reactor where an additional H 2 is produced from the reaction between the steam and carbon monoxide then, the mixture of gases goes through either a pressure swing adsorption or through a CO 2removal and methanation producing virtually pure H 2 [43]. Membrane reactors offer a remarkable solution.…”
Section: Methods Of Steam Reformingmentioning
confidence: 99%
“…The purge step significantly influences the carbon capture rate (CCR), as more steam desorbs more CO 2 product. Then, the pressure in the column is increased step by step during three pressure equalization steps, and finally, a repressurization step is done by using part of the H 2 product [23,24]. A schematic representation of an integrated steel mill with SEWGS technology is presented in Figure 2.…”
Section: Case Descriptionmentioning
confidence: 99%