High-Temperature Mechanical Spectroscopy of Nitrogen-Rich Ca-α-SiAlON Ceramics

Abstract

Nitrogen‐rich Ca–α‐SiAlON ceramics made with different starting powder compositions have been studied by high‐temperature mechanical spectroscopy in parallel with compressive deformation in a spark plasma sintering equipment. The mechanical loss spectra measured upon heating show a relaxation peak at about 1150 K and a high‐temperature exponential background at higher temperatures (>1400 K), which are attributed to the α‐relaxation in the glassy phase and to grain‐boundary sliding, respectively. A theoretical interpretation of the results shows that the peak position is mainly a function of glass viscosity. The amplitude of the peak is not only affected by the glassy phase quantity but also depends on the restoring force due to grain elasticity. Therefore, despite a higher amount of glassy phase specimens containing elongated grains may show a lower peak. The amplitude of the internal friction peak corresponding to α‐relaxation can be used to predict the compression creep of silicon‐nitride‐based ceramics.

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“…A similar shaped non-receivable mechanical loss spectrum has been reported for silicon nitride ceramics by Mehdi et al [18] where larger crystals were bounded by a glassy phase located between neighboring crystals as a glassy film or at triple grain junctions as glassy pockets. A broad peak during heating was observed around 1100 K, but the peak is not observed during the second heating.…”