High-temperature electrochemical hydrogen separation from reformate gases using PBI/MOF composite membrane

Durmuş, Gizem Nur Bulanık; Eren, Enis Oğuzhan; Devrim, Yılser; Çolpan, C. Özgür; Özkan, Necati

doi:10.1016/j.ijhydene.2023.03.192

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Cited by 5 publications

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“…The lower activation energy of Cu-BTC-Lys (43 wt%) falls within the energy range of the Grotthuss proton migration pathway, which involves proton hopping along formed hydrogen-bonding networks. 40,41 On the other hand, the other samples primarily followed the vehicle mechanism due to the limited Lys proton donors in the frameworks. The possible proton hopping routes are presented in Fig.…”

Section: Materials Characterizationmentioning

confidence: 99%

Enhanced proton conductivity in a Cu-BTC thin-film membrane through lysine incorporation and a mixed matrix membrane

Gao

Liu

et al. 2023

New J. Chem.

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Section: Materials Characterizationmentioning

confidence: 99%

Enhanced proton conductivity in a Cu-BTC thin-film membrane through lysine incorporation and a mixed matrix membrane

Gao

Liu

et al. 2023

New J. Chem.

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Recent Advancements in Metal‐Organic Framework‐Based Membranes for Hydrogen Separation: A Review

Baig,

Waheed,

Jillani

2023

Chemistry An Asian Journal

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Metal‐organic frameworks (MOFs) are promising porous materials that have huge potential for gas separation when put in the membrane configuration. MOFs have huge potential of the MOFs such as excellent pore size, ease of tuning the pore chemistry, higher surface area, and chemical and thermal stabilities, MOFs have been explored for various gas separation and storage applications. This review discusses various approaches for fabricating MOFs‐based membranes for the separation of H2 gas from a variety of feeds having various gases CO2, CO, N2, and CH4 as impurities. The emphasis has been put on three types of membranes for H2 separation which include MOFs‐based hollow fibrous/tubular/disk membranes, MOFs‐based mixed matrix membranes (MMMs), and MOFs‐based stand‐alone membranes. In addition, various challenges such as reducing inhomogeneity between MOFs and polymeric matrices have also been discussed. Similarly, the approaches to successfully decorating MOFs on different supports in different configurations have been explained. The possible ways of improving the MOFs‐based membranes for H2 have also been discussed.

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A roadmap of MOFs derived porous carbon, oxides, chalcogenides, and phosphides of metals: Synthesis, properties, parameter modulation and their utilization as an electrode for Li/Na/K-ion batteries

Kitchamsetti,

Cho

2024

Journal of Energy Storage

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High-temperature electrochemical hydrogen separation from reformate gases using PBI/MOF composite membrane

Cited by 5 publications

References 51 publications

Enhanced proton conductivity in a Cu-BTC thin-film membrane through lysine incorporation and a mixed matrix membrane

Enhanced proton conductivity in a Cu-BTC thin-film membrane through lysine incorporation and a mixed matrix membrane

Recent Advancements in Metal‐Organic Framework‐Based Membranes for Hydrogen Separation: A Review

A roadmap of MOFs derived porous carbon, oxides, chalcogenides, and phosphides of metals: Synthesis, properties, parameter modulation and their utilization as an electrode for Li/Na/K-ion batteries

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