1987
DOI: 10.1016/0001-6160(87)90052-6
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High-temperature deformation of MnO

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Cited by 13 publications
(5 citation statements)
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“…This is about a factor of two higher than the CRSS extrapolated to 0 K, but should be considered to be in satisfactory agreement in terms of the computing techniques of the time. 9.4.1.2 Transition Metal Oxides and the Effect of Stoichiometry Plastic deformation of single crystals of the transition metal oxides M 1-x O with the rock-salt structure has been studied for M ¼ Mn [43], Fe [44], Co [45][46][47][48], and Ni [49,50]. The maximum value of x varies from 0.001 for Ni and 0.013 for Co to 0.15 for Fe and Mn.…”
Section: Dislocations In Particular Oxidesmentioning
confidence: 99%
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“…This is about a factor of two higher than the CRSS extrapolated to 0 K, but should be considered to be in satisfactory agreement in terms of the computing techniques of the time. 9.4.1.2 Transition Metal Oxides and the Effect of Stoichiometry Plastic deformation of single crystals of the transition metal oxides M 1-x O with the rock-salt structure has been studied for M ¼ Mn [43], Fe [44], Co [45][46][47][48], and Ni [49,50]. The maximum value of x varies from 0.001 for Ni and 0.013 for Co to 0.15 for Fe and Mn.…”
Section: Dislocations In Particular Oxidesmentioning
confidence: 99%
“…It is a different story at high temperatures, where there have been a number of studies of the influence of stoichiometry on the creep rate [43-45, 47, 49] or the flow stress [43,47]. Typically, for a given applied stress, the creep rate increases with increasing p O2 , that is, as the crystals become more stoichiometric (i.e., as x decreases).…”
Section: Dislocations In Particular Oxidesmentioning
confidence: 99%
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“…7'19 However, for CoO, FeO, MnO and NiO, the cation defects dominate and the minority defects, of either oxygen vacancies or interstitials, control the creep rates. 11,12,14,19,[21][22][23] It can be presumed by analogy that oxygen defects move more slowly than cation defects in CuO and, therefore, control creep; oxygen ions are larger than copper ions. 15…”
Section: Dicussionmentioning
confidence: 99%
“…The steady-state deformation of Mnl.xO single crystals has been investigated over a wide range of T and Po_ [10,13,14] The activation energies for tracer diffusion of O along the c-axis, and for Ag in polycrystalline material, the only other cation measured, are 212 and 181 kJ/mole, respectively. It has been postulated that Ca is the rate--controlling species [23].…”
Section: Mnlxomentioning
confidence: 99%