High-Strength Titanium-Based Alloy for Low-Temperature Superplastic Forming

Mikhaylovskaya, A. V.; Mosleh, Ahmed O.; Mestre-Rinn, P.; Котов, А. Д.; Ситкина, М. Н.; Базлов, А. И.; Louzguine-Luzgin, Dmitri V.

doi:10.1007/s11661-020-06058-8

Cited by 12 publications

(8 citation statements)

References 60 publications

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“…Alloying with 0.1%B provided a globular microstructure in the alloy and twice decreased LAGB fraction. A similar effect was found due to alloying of Ti-Al-Mo-V alloy by both Fe and B [39]. Thus, boron plays a key role in the acceleration of the recrystallization and further globularization of the grains.…”

Section: Discussionsupporting

confidence: 65%

“…Due to grain refinement, a trace addition of 0.1%B improves superplastic properties and increases the superplastic formability of the Ti-6Al-4V alloy [28]. The complex alloying with B and Fe improves superplasticity and decreases superplastic deformation temperature for Ti-4Al-3Mo-1V alloy but the effect of B for complexly alloyed materials is not clear [39,40]. This work studies the influence of boron in a range of 0.01-2 wt.% on the microstructure, superplasticity, and mechanical properties at room temperature of the Ti-4Al-3Mo-1V.…”

Section: Introductionmentioning

confidence: 99%

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Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Postnikova¹,

Котов²,

Базлов³

et al. 2023

Preprint

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The microstructure evolution, superplasticity, and room temperature mechanical properties of Ti-4%Al-1%V-3%Mo alloys modified with 0.01-2 wt.% boron were investigated. Increasing the boron content from 0 to 0.1 wt.% effectively refined prior β-grains, reducing a mean grain size from ~700 µm to ~210 µm. Whiskers of the TiB phase with a size in a range of 0.7-2.9 µm were observed after solidification and thermomechanical processing. Alloys with 0.01-0.1 wt.% boron exhibited similar superplastic elongations and strain rate sensitivity coefficient m of 0.4-0.5 at a strain rate of 1×10-3 s-1 and the elongation to failure decreased from 1000% at 875°С to 400-500% at 700°С. Along with this, the minor boron addition effectively decreased flow stress values, especially at 775 °C, that was explained by the acceleration of the recrystallization and globularization of the microstructure at the initial stage of deformation. Recrystallization-induced decrease in yield strength from 770 MPa to 680 MPa was observed with an increase in boron content from 0 to 0.1 wt.%. Heat treatment increased post-forming strength characteristics for the alloys with 0.01-0.1 wt.% boron by 90–140 MPa without ductility reduction. Alloys with 1-2 wt.% B demonstrated the opposite behavior. The grain refinement effect was not revealed, and prior β grain sizes were ~670-750 µm after solidification. Thermomechanical processing promoted the fragmentation of boride whiskers and the formation of near-spherical particles with a size of ~1 μm for the alloy with a eutectic concentration of 2 wt.% B. A high fraction of borides, ~5-11%, in the alloys with 1-2 wt.% B deteriorated the superplastic properties and drastically decreased ductility at room temperature. The alloy with 2 wt.% B demonstrated non-superplastic behavior and a low level of mechanical properties, meanwhile, the alloy with 1% boron exhibited high-temperature superplasticity at 875 °C with elongation of ~500%, and yield strength of 830 MPa, ultimate tensile strength of 1020 MPa at a room temperature after 100% of superplastic deformation.

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Section: Discussionsupporting

confidence: 65%

Section: Introductionmentioning

confidence: 99%

Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Postnikova¹,

Котов²,

Базлов³

et al. 2023

Preprint

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“…The mean grain size decreased more than three times ( Table 2 ). The grain refinement effect of 0.02–0.2% boron is well known for unalloyed Ti [ 38 ], several Ti-based alloys [ 16 , 24 ], and Ti-Ni [ 39 , 40 ] and Ti-Al [ 41 , 42 , 43 ] intermetallic alloys. The difference in the grain size between 0.1 and 0.4 wt.% B was insignificant.…”

Section: Discussionmentioning

confidence: 99%

“…Due to grain refinement, a trace addition of 0.1% B improves superplastic properties and increases the superplastic formability of the Ti-6Al-4V alloy [ 28 ]. The complex alloying with B and Fe improves superplasticity and decreases superplastic deformation temperature for Ti-4Al-3Mo-1V alloy, but the effect of B for complexly alloyed materials is not clear [ 38 ]. This work studies the influence of boron in a range of 0.01–2% on the microstructure, superplasticity, and mechanical properties at room temperature of Ti-4Al-3Mo-1V.…”

Section: Introductionmentioning

confidence: 99%

Effect of Boron on the Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

et al. 2023

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The decrease of superplastic forming temperature and improvement of post-forming mechanical properties are important issues for titanium-based alloys. Ultrafine-grained and homogeneous microstructure are required to improve both processing and mechanical properties. This study focuses on the influence of 0.01–2 wt.% B (boron) on the microstructure and properties of Ti-4Al-3Mo-1V (wt.%) alloys. The microstructure evolution, superplasticity, and room temperature mechanical properties of boron-free and boron-modified alloys were investigated using light optical microscopy, scanning electron microscopy, electron backscatter diffraction, X-ray diffraction analysis, and uniaxial tensile tests. A trace addition of 0.01 to 0.1 wt.% B significantly refined prior β-grains and improved superplasticity. Alloys with minor B and B-free alloy exhibited similar superplastic elongations of 400–1000% in a temperature range of 700–875 °C and strain rate sensitivity coefficient m of 0.4–0.5. Along with this, a trace boron addition provided a stable flow and effectively reduced flow stress values, especially at low temperatures, that was explained by the acceleration of the recrystallization and globularization of the microstructure at the initial stage of superplastic deformation. Recrystallization-induced decrease in yield strength from 770 MPa to 680 MPa was observed with an increase in boron content from 0 to 0.1%. Post-forming heat treatment, including quenching and ageing, increased strength characteristics of the alloys with 0.01 and 0.1% boron by 90–140 MPa and insignificantly decreased ductility. Alloys with 1–2% B exhibited an opposite behavior. For the high-boron alloys, the refinement effect of the prior β-grains was not detected. A high fraction of borides of ~5–11% deteriorated the superplastic properties and drastically decreased ductility at room temperature. The alloy with 2% B demonstrated non-superplastic behavior and low level of strength properties; meanwhile, the alloy with 1% B exhibited superplasticity at 875 °C with elongation of ~500%, post-forming yield strength of 830 MPa, and ultimate tensile strength of 1020 MPa at room temperature. The differences between minor boron and high boron influence on the grain structure and properties were discussed and the mechanisms of the boron influence were suggested.

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“…Various methods of deformation treatment (e.g., various severe plastic deformation (SPD) methods) are often applied to improve strength and corrosion resistance of the Ti alloys [10][11][12]. In recent years, modification of the chemical composition of the Ti alloys (e.g., by doping with Pt-group metals) are also applied to improve strength and corrosion resistance of the ones [13,14].…”

Section: Introductionmentioning

confidence: 99%

Investigation of Microstructure and Corrosion Resistance of Ti-Al-V Titanium Alloys Obtained by Spark Plasma Sintering

Нохрин

Андреев

Болдин

et al. 2021

Metals

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The research results of the microstructure and corrosion resistance of Ti and Ti-Al-V Russian industrial titanium alloys obtained by spark plasma sintering (SPS) are described. Investigations of the microstructure, phase composition, hardness, tensile strength, electrochemical corrosion resistance and hot salt corrosion of Ti-Al-V titanium alloy specimens were carried out. It was shown that the alloy specimens have a uniform highly dense microstructure and high hardness values. The studied alloys also have high resistance to electrochemical corrosion during tests in acidic aqueous solution causing the intergranular corrosion as well as high resistance to the hot salt corrosion. The assumption that the high hardness of the alloys as well as the differences in the corrosion resistance of the central and lateral parts of the specimens are due to the diffusion of carbon from the graphite mold into the specimen surface was suggested.

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High-Strength Titanium-Based Alloy for Low-Temperature Superplastic Forming

Cited by 12 publications

References 60 publications

Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Boron Effect on Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Effect of Boron on the Microstructure, Superplastic Behavior, and Mechanical Properties of Ti-4Al-3Mo-1V Alloy

Investigation of Microstructure and Corrosion Resistance of Ti-Al-V Titanium Alloys Obtained by Spark Plasma Sintering

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