“…These values are similar to the corresponding ones for BiH (14). The small negative value for b F is consistent with the unpaired electron being assigned to a p orbital; it is a »0ÉBL 0 Én… Ç 2B…”
Section: (Iii) Interpretation Of Electron Spin Parameters L G and Hysupporting
confidence: 79%
“…The analysis proceeds in a manner similar to that described for BiH (14) except that excited state, there are smaller splittings in the ground state the assignment of F values to the hyperfine components is based on intensity considerations. In general the strongest which have to be considered.…”
Section: Discussionmentioning
confidence: 99%
“…This value agrees well with the observed would be expected to be larger than for BiF whereas exseparation of 26 000 cm 01 ( 3 ) . However, we note that perimentally it is found to be smaller ( 0.040 cm 01 ) (14 ) . the spin -spin parameter l for BiH ( 2473.4 cm 01 ) is apTwo magnetic hyperfine parameters have been determined preciably smaller than the value for BiF ( 3384.1 cm 01 ) , for BiF involving its ground state, viz.…”
Section: (Iii) Interpretation Of Electron Spin Parameters L G and Hymentioning
“…These values are similar to the corresponding ones for BiH (14). The small negative value for b F is consistent with the unpaired electron being assigned to a p orbital; it is a »0ÉBL 0 Én… Ç 2B…”
Section: (Iii) Interpretation Of Electron Spin Parameters L G and Hysupporting
confidence: 79%
“…The analysis proceeds in a manner similar to that described for BiH (14) except that excited state, there are smaller splittings in the ground state the assignment of F values to the hyperfine components is based on intensity considerations. In general the strongest which have to be considered.…”
Section: Discussionmentioning
confidence: 99%
“…This value agrees well with the observed would be expected to be larger than for BiF whereas exseparation of 26 000 cm 01 ( 3 ) . However, we note that perimentally it is found to be smaller ( 0.040 cm 01 ) (14 ) . the spin -spin parameter l for BiH ( 2473.4 cm 01 ) is apTwo magnetic hyperfine parameters have been determined preciably smaller than the value for BiF ( 3384.1 cm 01 ) , for BiF involving its ground state, viz.…”
Section: (Iii) Interpretation Of Electron Spin Parameters L G and Hymentioning
“…The electronic states and spectra of the five monohydrides and 20 monohalides of group Va elements have been the subject of numerous studies (1,(2)(3)(4)(5)(6)(7)(8), and references cited therein). Their lowest lying electron configurations .…”
“…Examples are TeH (72) and BiH (73), which have -II and 32 ground states respectively. Also the series HO,, HS,, HSe2, and HTe, has given extensive spectra.…”
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