High‐resolution stimulated Raman spectroscopy of low‐frequency rotational transitions: Obtention of collisional broadening coefficients in the rotational S branch of CO perturbed by H2
Abstract:We demonstrate the application of high‐resolution quasi‐continuous (q‐cw) stimulated Raman spectroscopy (SRS) to the study of low‐frequency, pure rotational transitions of molecules in diluted samples in order to obtain collisional information. The main problems encountered in the few pioneering q‐cw SRS rotational works, namely weak signals because of the small population differences between the upper and lower states of the transitions and the presence of alternating current (AC) Stark effect, have been addr… Show more
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