We reveal the existence of high-density Feshbach resonances in the collision between the ground and metastable states of 171 Yb and coherently produce the associated Feshbach molecules by photoassociation. The extremely small transition rate is overcome by the enhanced Franck-Condon factor of the weakly bound Feshbach molecule, allowing us to observe Rabi oscillations with long decay time between an atom pair and a molecule in an optical lattice. We also perform the precision measurement of the binding energies, which characterizes the observed resonances. The ultra-narrow photoassociation will be a basis for practical implementation of optical Feshbach resonances. [2][3][4], the initial step to form an ultracold, ro-vibronic ground state of (polar) molecules [5,6], correlation measurements for ultracold atoms in an optical lattice [7][8][9], and so on. Photoassociation (PA) is another standard method to generate ultracold molecules which can create various molecules in electronic excited states with a simple optical excitation. [10]. However, the transition probability is never large enough even for a strong electric-dipole allowed (E1) transition due to small overlap between the wave functions of free atoms and molecular bound states, resulting in small FranckCondon factors. In addition, the radiative lifetime of the created molecular states is usually quite short for an E1 transition. As a consequence, coherent production of molecules by one-color PA has been impossible until recent demonstration with a BEC of 88 Sr [11], where the narrow 1 S 0 ↔ 3 P 1 transition was exploited.In this Letter, we report on photoassociative creation of ultracold molecules associated with the ground 1 S 0 and long-lived metastable 3 P 2 states of 171 Yb with a radiative lifetime of longer than one second. Importantly, the otherwise quite small strength of the PA resonance is significantly enhanced by working around FRs for the closed channel. This enables us to demonstrate Rabi oscillations in the PA transition with a lifetime reaching hundreds of microseconds. Moreover, by using this narrow-line PA, observed FRs are characterized by precise measurement of the binding energies of near-threshold Fesbach molecules. Our observation of the strong PA line with a long expected radiative lifetime opens up the possibility to suppress atom loss in optical Feshbach resonances [11][12][13].First, we describe our observation of FRs in collisions between 1 S 0 and 3 P 2 states of 171 Yb, which is an important basis in this work. Most of the currently studied FRs are for alkali atoms, which originate from their hyperfine structures with isotropic van der Waals interactions. On the other hand, the emergence of FRs associated with the existence of anisotropic interactions was recently predicted [14] and observed in collisions of Er [15] and Dy [16]. For these atoms, anisotropy in an electrostatic van der Waals potentials with non-zero electronic orbital angular momenta as well as dipole-dipole interactions induces couplings between an open cha...