High resolution infrared study of the parallel band ν3of chloroform CH35Cl3

Pietilä, J.; Horneman, V.‐M.; Anttila, R.

doi:10.1080/00268979909483089

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2002

2012

Publication Types

Select...

Article3

Other1

Book1

Relationship

Self Cite0

Independent5

Authors

Journals

Cited by 14 publications

References 9 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Mass and Isotope‐Selective Infrared Spectroscopy

Hippler¹,

Miloglyadov²,

Qüack³

et al. 2011

Handbook of High‐resolution Spectroscopy

View full text Add to dashboard Cite

Recent advances in laser spectroscopic techniques make it possible to obtain mass‐ and isotope‐selective infrared spectra of gas‐phase species at high resolution and reduced hot‐band spectral congestion. In these techniques, infrared excitation is coupled with ultraviolet multiphoton ionization and detection of the resulting ions in a mass spectrometer, which allows the separation of contributions of different isotopomers and, more generally, species of different mass in a mixture. In combination with jet cooling techniques, spectra are obtained for very cold molecules. These spectra can then be analyzed to extract information on dynamical processes such as intramolecular vibrational redistribution or tunneling and rearrangement processes, and on how intramolecular dynamics is influenced by vibrational excitation and isotope effects. In this review, we introduce isotope‐selective infrared spectroscopic techniques and present some selected applications on isotope effects and intramolecular dynamics of vibrationally excited chloroform, aniline, and benzene obtained by isotope‐selective infrared spectroscopy.

show abstract