High resolution infrared spectra of the first and second stretching overtone band systems of 123SbD3

High resolution infrared study of SbHD2: The ground state and the Sb–H stretching bands ν1 and 2ν1

“…Indeed, the local mode model reproduced very well the characteristic behavior of stretching states up to high excitation [6][7][8].…”

“…(2)(3)(4)(5)(6)(7)(8)(9) ratios between x 0 i and between x 0 ij values for 123 SbH 2 D and 123 SbHD 2 have been derived, Table 4. Numerical results from expanded local mode theory (''ELMT'') [20] are listed in Table 4, columns 2 and 4.…”

“…Spectral bands of the SbHD 2 molecule were searched in the high resolution infrared spectra of mono-isotopic 123 SbD 3 [2,8] and of natural SbD 3 [3] recorded at Wuppertal with a Bruker 120HR interferometer. These spectra had been previously explored in the regions of pure rotation and of the fundamentals [2,3] and of Sb-D stretching overtone bands [8].…”

“…These spectra had been previously explored in the regions of pure rotation and of the fundamentals [2,3] and of Sb-D stretching overtone bands [8]. Owing to a ca.…”

“…Experimental details of the three spectra I, II, and III used for the search for SbHD 2 have been reported earlier [2,3,8] and are therefore repeated only briefly in the following.…”