High rate, high temperature, dendrite free plating/stripping of Li in 3-dimensional honeycomb boron carbon nitride to realize an ultrastable lithium metal anode

Patrike, Apurva; Karbhal, Indrapal; Wasnik, Kundan; Torris, Arun; Maibam, Ashakiran; Krishnamurty, Saïlaja; Shelke, Manjusha V.

doi:10.1016/j.est.2023.107547

Cited by 3 publications

(4 citation statements)

References 54 publications

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“…It is very difficult to obtain a 3D porous architecture having a ternary B−C−N morphology; however, these BCN systems have higher capability to replace currently available graphite anode materials in LIBs and hold higher capacity than graphite. 59 Most of the BCN materials reported in the literature are 1D tube or 2D graphene sheet-like structures. The performance of BCN can be improved by preparing a 3D porous structure because 3D porous structures have efficient properties for LIBs, such as higher pore volume for improving Li intake capability, higher surface area for providing efficient electrode−electrolyte contact, and tunability in pore size to facilitate fast charge transfer and ample reduction to the polarization effect.…”

Section: Li-ion Battery (Lib)mentioning

confidence: 99%

“…3D BCN, having a porous morphology and carbonaceous architecture, has limited reports in the literature. It is very difficult to obtain a 3D porous architecture having a ternary B–C–N morphology; however, these BCN systems have higher capability to replace currently available graphite anode materials in LIBs and hold higher capacity than graphite . Most of the BCN materials reported in the literature are 1D tube or 2D graphene sheet-like structures.…”

Section: Applications Of Boron Carbon Nitride In Rechargeable Batteriesmentioning

confidence: 99%

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Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Thomas,

Cherusseri,

Pallavolu

et al. 2024

Energy Fuels

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Boron carbon nitride (BCN) is a prominent ultrathin two-dimensional (2D) material that has received significant attention in the recent past. BCN possesses unique properties such as good electronic conductivity, layered 2D architecture, large surface area, good chemical and electrochemical stabilities, etc. Rechargeable batteries, such as lithiumion batteries (LIBs), have made a technological revolution in the field of electrochemical energy storage devices. Electrode materials with layered 2D architectures are highly preferred for application in rechargeable batteries. BCN-based electrodes are potential candidates for rechargeable battery applications and have motivated us to write this review on BCN as an emerging electrode material for applications in batteries. This review discusses the potential of BCN-based materials for rechargeable battery applications and the lack of these materials in the literature. Initially, we discuss the crystal structure of BCN. Further, the various available methods to synthesize BCN nanostructures such as hydrothermal methods, chemical vapor deposition, and pyrolysis, to name a few, are discussed. Additionally, the electrode applications of BCN-based materials for LIBs, Zn−air batteries, Li−O 2 batteries, Li−sulfur batteries, etc., are reviewed in detail. The present review proclaims the development of novel hierarchical layered 2D BCN-based materials for potential applications in next-generation rechargeable batteries. In addition, it emphasizes the difficulties and potential uses of BCN energy storage systems in the future.

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Section: Li-ion Battery (Lib)mentioning

confidence: 99%

Section: Applications Of Boron Carbon Nitride In Rechargeable Batteriesmentioning

confidence: 99%

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Thomas,

Cherusseri,

Pallavolu

et al. 2024

Energy Fuels

View full text Add to dashboard Cite

show abstract

“…However, traditional anode materials, like graphite, are hampered by a specific capacity limit of 372 mAh g −1 , rendering them inadequate for future demands. 5,6 Consequently, there is an increasing need for LIBs with high energy and power densities coupled with rapid charging capabilities. 7−9 Addressing these demands poses challenges, given the limitations of conventional materials, which face increased charge transfer constraints as well as resistance in thicker electrodes.…”

Section: Introductionmentioning

confidence: 99%

“…Since their emergence in the 1990s, lithium-ion batteries (LIBs) have garnered significant attention, becoming indispensable power sources in electric vehicles and portable electronics. − Among the components of LIBs, the anode plays a critical role in dictating electrochemical performance. However, traditional anode materials, like graphite, are hampered by a specific capacity limit of 372 mAh g –1 , rendering them inadequate for future demands. , Consequently, there is an increasing need for LIBs with high energy and power densities coupled with rapid charging capabilities. − Addressing these demands poses challenges, given the limitations of conventional materials, which face increased charge transfer constraints as well as resistance in thicker electrodes . To tackle this, a common strategy involves the integration of high-capacity materials to reduce electrode size.…”

Section: Introductionmentioning

confidence: 99%

N-Doped Hollow Multichannel Carbon Nanofibers Encased in Fe₃C for Lithium-Ion Storage

Cheng,

Lu,

Zhang

et al. 2024

ACS Appl. Nano Mater.

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In advancing lithium-ion batteries to achieve high energy densities, prolonged cycling lifespan, and enhanced charging rates, electrode materials with high specific capacities play a crucial role. In this study, we have developed a porous carbon substrate using coaxial electrostatic spinning to enhance the electrochemical properties of the carbon-based anode. This porous structure exposes numerous active sites for Li + ions and reduces the Li + /e − transport pathway, thereby improving the kinetics of Li + /ion and electron transfer. The symbiotic interaction between N and Fe 3 C nanoparticles facilitates the formation of hollow channels and dual conductive pathways. These Fe 3 C nanoparticles, along with hollow carbon nanofibers, enhance long-term cycling stability at room temperature, promote the formation of stable SEI layers, and improve interfacial compatibility. The Fe 3 C hollow multichannel carbon fibers (Fe 3 C/HMCFs) were subjected to analysis using a magnetic measurement system to investigate the charge transfer phenomenon. The observed charge transfer behavior confirms the conductivity of the magnetic Fe 3 C materials. These Fe 3 C/HMCFs exhibit favorable electrochemical characteristics, including an initial capacity of 1130 mAh g −1 at a current density of 2 A g −1 and a second charge/discharge capacity of 706 mAh g −1 .

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An ultrathin and robust single-ion conducting interfacial layer for dendrite-free lithium metal batteries

Lv,

Liu,

et al. 2024

Journal of Energy Chemistry

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High rate, high temperature, dendrite free plating/stripping of Li in 3-dimensional honeycomb boron carbon nitride to realize an ultrastable lithium metal anode

Cited by 3 publications

References 54 publications

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

N-Doped Hollow Multichannel Carbon Nanofibers Encased in Fe₃C for Lithium-Ion Storage

An ultrathin and robust single-ion conducting interfacial layer for dendrite-free lithium metal batteries

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High rate, high temperature, dendrite free plating/stripping of Li in 3-dimensional honeycomb boron carbon nitride to realize an ultrastable lithium metal anode

Cited by 3 publications

References 54 publications

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

Boron Carbon Nitride (BCN): An Emerging Two-Dimensional Material for Rechargeable Batteries

N-Doped Hollow Multichannel Carbon Nanofibers Encased in Fe3C for Lithium-Ion Storage

An ultrathin and robust single-ion conducting interfacial layer for dendrite-free lithium metal batteries

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N-Doped Hollow Multichannel Carbon Nanofibers Encased in Fe₃C for Lithium-Ion Storage