2019
DOI: 10.1016/j.surfin.2019.100367
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High proportion ZnO/CuO nanocomposites: Synthesis, structural and optical properties, and their photocatalytic behavior

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Cited by 45 publications
(26 citation statements)
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“…All of the HPTS based sensing slides exhibited good carbon dioxide sensitivity (I0/I100), regression coefficients, and KSV values for the concentration range of 0-100% p[CO2]. (21). In our study, unlike the ZCO-CS, the Zn amount is higher for the ZCO-H heterostructure (confirmed by XPS).…”
Section: Co2 Induced Response Of Hpts Based Sensing Slidessupporting
confidence: 65%
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“…All of the HPTS based sensing slides exhibited good carbon dioxide sensitivity (I0/I100), regression coefficients, and KSV values for the concentration range of 0-100% p[CO2]. (21). In our study, unlike the ZCO-CS, the Zn amount is higher for the ZCO-H heterostructure (confirmed by XPS).…”
Section: Co2 Induced Response Of Hpts Based Sensing Slidessupporting
confidence: 65%
“…The mechanism underlying the strong emission and absorption capabilities of the ZnO/CuO heterostructure involves bandgap excitation by energetic photons that produce holes in the crystalline valence band and exciton pairs with electrons in the conduction band. Also, the p-n hetero formation plays an important role in improving the detection performance (21,24). However, it can also be attributed to the larger depletion layer on the CuO/ZnO surface, which results from the formation of p-n heterojunctions between the p-CuO and n-type ZnO particles (24).…”
Section: Emission and Excitation Spectra Of Hpts And The Utilized Metal Oxide Powdersmentioning
confidence: 99%
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“…Figure 5 represents the Raman spectrum of the nanoprepared samples. Using group theory, CuO possesses 12 zone centers at the point Γ of the Brillouin zone (BZ), (Au+2Bu) are acoustic modes, (3Au+3Bg) are infrared modes and (Ag+2Bg) are the modes of Raman active [37]. Due to the symmetry of the site in copper oxide, the displacement of oxygen atoms contributes to the three active modes, while the atoms of Cu remain constant and ineffective for the Raman modes.…”
Section: Raman Studiesmentioning
confidence: 99%
“…Constructing heterostructures by combining noble metal crystal with semiconductor can be a potential answer for this problem, due to their higher work function than most of the semiconductors for accepting photogenerated electrons from semiconductors and thus enhancing the photogenerated charge carrier separation efficiency. [25][26][27][28][29] In addition, plasmonic noble metals, such as Ag and Au, possess unique surface plasmon resonance (SPR) properties, allowing them to simultaneously facilitate the photogenerated charge carrier separation efficiency and provide SPR-induced "hot electron" for the photocatalytic reaction. 28,[30][31][32] The surface plasmon may improve the photocatalytic activities via local electromagnetic eld enhancement and resonant energy transfer (RET) mechanisms.…”
Section: Introductionmentioning
confidence: 99%