“…The aligning materials, both the organic and inorganic ones, cover the substrates and ensure an orienting process in the LC material thanks to their anisotropic properties. Anisotropy in layers may be generated in such physicochemical processes as: laser writing [2], silica oxide deposition [3,4], microrubbing [5], plasma beam irradiation [6], ion-beam irradiation [7], photoalignment, PA, Langmuir-Blodgett layer deposition [8], usage of dendrimer-like structures with azo-moieties attached [9], or with an ordinarily used technique-rubbing. Each of the processes mentioned above has its advantages and disadvantages in preparation of liquid crystal devices, dependent on their further utilisation.…”