“…Wichterle (1977Wichterle ( , 1978 in a general study of gas-liquid equilibria has illustrated terminations of azeotrope curves along unary curves and at critical curves. One of the series of T-X sections of fluid mixtures calculated by Van Konynenburg and Scott (1980) contains a sequence of isobaric sections, analogous to the transition from Figure 4d to 4e, in which the solubility order of gas and liquid at a 3-phase equilibrium changes with appearance of an azeotrope (Van Konynenburg and Scott, 1980;their Fig.…”
“…Wichterle (1977Wichterle ( , 1978 in a general study of gas-liquid equilibria has illustrated terminations of azeotrope curves along unary curves and at critical curves. One of the series of T-X sections of fluid mixtures calculated by Van Konynenburg and Scott (1980) contains a sequence of isobaric sections, analogous to the transition from Figure 4d to 4e, in which the solubility order of gas and liquid at a 3-phase equilibrium changes with appearance of an azeotrope (Van Konynenburg and Scott, 1980;their Fig.…”
“…Schneider en 1963 [128,129] descubrión experimentalmente el diagrama de fase tipo V I. Cabe aclarar que si bien hemos presentado este tema de inmiscibilidad líquido-líquido, cuando las temperaturas y presiones son elevadas, las regiones descritas pueden corresponder a inmiscibilidad gas-gas. Ivan Wichterle [130][131][132][133][134][135] se refiere en una forma más general a la región de coexistencia fluido-fluido, significando líquido-líquido o gas-gas, dependiendo de la temperatura y la presión. La forma y posición de la región de coexistencia l − g están fijas en la práctica por las curvas de presión de saturación de los componentes puros y por los valores de las constantes críticas.…”
High-pressure isothermal vapor liquid equilibrium data were measured for the propane-1-propanol system at 81.6, 105.2, and 120.l"C in ( Skjold-Jorgenson, 19861, Peng-Robinson EOS (Peng Robinson, 1976)
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