High-pressure, high-temperature synthesis of nanostructured polydiphenylbutadiyne confined in the 1-dimensional pores of single crystal AlPO₄-54

Abstract

The π-conjugated, polymer polydiphenylbutadiyne was prepared at the nanoscale confined inside the 1.2 nm 1-D pores of the aluminophosphate AlPO4-54. Molten 1,4-diphenyl-1,3-dibutadiyne (DPB) was inserted in the pores of AlPO4-54...