Abstract:<p>High
pressure high temperature (HPHT) synthesis of crystallographically well-defined
boron doped diamond (BDD) microparticles, suitable for electrochemical
applications and using the lowest P and T (5.5 GPa and 1200°C) growth conditions to date, is reported. This is aided through the use
of a metal (Fe-Ni) carbide forming catalyst and an aluminum
dibromide (AlB<sub>2</sub>) boron source. The latter also acts as a nitrogen sequester, to reduce
boron-nitrogen charge compensation effects. Ram… Show more
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