Detailed spectroscopic measurements of excited states in 50 Cr and 62 Zn were performed using 24 MeV (p,t) transfer reactions on 52 Cr and 64 Zn, respectively. In total, forty-five states in 50 Cr and sixty-seven states in 62 Zn were observed up to excitation energies of 5.5 MeV, including several previously unobserved states. These experimental results are compared to ab-initio shell-model calculations using chiral effective field theory (χ-EFT) with the valence-space in-medium similarity renormalization group (VS-IMSRG) method. This comparison demonstrates good agreement in the level orderings with these new theoretical methods, albeit with a slight over binding in the calculations. This work is part of a continued push to benchmark ab-initio theoretical techniques to nuclear structure data in 0 + → 0 + superallowed Fermi β decay systems.