A novel asymmetrical twin-core photonic crystal fiber was proposed, whose effective overlap core area A eff can be designed to synchronize the variation of Raman gain coefficient with respect to frequency. This fiber possesses a higher and flatter Raman gain efficiency coefficient curve r R =g R /A eff over a specified band of wavelength than a conventional fiber. Therefore, it is a good candidate of gain medium for a flat, broad gain band fiber Raman amplifier. It was numerically demonstrated that for the Raman gain efficiency r R , relative fluctuations of less than 2.2% and 5.7% are achievable in the C (1530-1565 nm) band and L (1565-1625 nm) band, respectively.Raman gain, photonic crystal fiber, effective overlap core area, Raman amplifierIn fiber optical communication, fiber losses damp the optical pulses so that pulse error rate increases with distance. This puts an ultimate limit on the un-relayed communication distance of the system. Currently, the fiber loss rate has almost reached its theoretical limit. Without a revolutionary breakthrough in fabrication technology, further reduction in fiber loss is very difficult. Therefore, attention is turned to optical amplifier for help. Optical amplifier is an important active device in modern fiber communication system to compensate for transmission loss. Among the various types of optical amplifiers, fiber Raman amplifier (FRA) is one of the key active elements in WDM fiber communication system because of its good noise performance, flexible gain band, and broad band of amplification [1][2][3] . In recent years, the fabrication technology of pump laser for FRA matures quickly. In the mean time, more and more shortcomings of EDFA in bandwidth and noise become apparent with the increase of communication capacity. Due to these reasons, FRA becomes a hot research topic, and relevant research papers and patents increase every year [4][5][6] .For the application of FRA in WDM system, a flat gain efficiency coefficient for a broad band of frequency is a desirable feature. When ordinary silica fiber is used as the gain medium, its intrinsic Raman gain coefficient g R is small and fluctuant as shown in Figure 1 [7] . In its usable frequency band, the effective overlap core area A eff is almost a constant, therefore, the resulting Raman gain efficiency coefficient r R =g R /A eff varies significantly with frequency. One way to overcome this demerit is to use multiple sources to pump simultaneously at different frequencies so that a flat gain spectrum can be resulted. However, such arrangement has drawbacks such as higher cost and lower reliability, because it significantly increases the complexity of the amplifier. A comprehensive design strategy is needed to carefully allocate the power level and wavelength of the multiple pumps, and to take care of the interactions between the sources [8][9][10][11][12][13] . In order to avoid the above mentioned difficulties, a novel asymmetrical twin-core photonic crystal fiber (ATC-PCF) was proposed as the gain medium in this work. ...