Abstract:Large-size composite carbon nanotubes/polyaniline as supercapacitor electrode material has been investigated for optimization of the areal specific capacitance. Polyaniline, as conductive polymer, is synthesized on the structure of carbon nanotubes by an in situ method. Thicker the composite electrode and higher polyaniline loading increase the gravimetric and volumetric specific capacitance. It is noticeable that this report's areal specific capacitance can reach approximately 6.5 F cm −2 .
“…[8][9][10][11][12][13] Due to their outstanding mechanical, 14,15 thermal, 16 and electrical properties 17,18 and chemical stability, 19,20 BPs have broad potential applications in electrode materials, filters, sensors, actuators and multifunctional devices. [21][22][23] Ever since the BP was first fabricated by Liu et al in 1998, 24 researchers have made great efforts to explore its mechanical properties using experimental and theoretical calculations. [25][26][27][28][29][30][31] Computer simulations such as ab initio molecular dynamics and classic molecular dynamics have been extensively used to study the mechanical properties of carbon based nanostructured material systems and several important achievements have been obtained.…”
Section: Introductionmentioning
confidence: 99%
“…8–13 Due to their outstanding mechanical, 14,15 thermal, 16 and electrical properties 17,18 and chemical stability, 19,20 BPs have broad potential applications in electrode materials, filters, sensors, actuators and multifunctional devices. 21–23…”
It is well-known that traditional Buckypaper (BP) is composed of a certain number of short carbon nanotubes (CNTs) intertwined with each other and sliding always happens when BP is under...
“…[8][9][10][11][12][13] Due to their outstanding mechanical, 14,15 thermal, 16 and electrical properties 17,18 and chemical stability, 19,20 BPs have broad potential applications in electrode materials, filters, sensors, actuators and multifunctional devices. [21][22][23] Ever since the BP was first fabricated by Liu et al in 1998, 24 researchers have made great efforts to explore its mechanical properties using experimental and theoretical calculations. [25][26][27][28][29][30][31] Computer simulations such as ab initio molecular dynamics and classic molecular dynamics have been extensively used to study the mechanical properties of carbon based nanostructured material systems and several important achievements have been obtained.…”
Section: Introductionmentioning
confidence: 99%
“…8–13 Due to their outstanding mechanical, 14,15 thermal, 16 and electrical properties 17,18 and chemical stability, 19,20 BPs have broad potential applications in electrode materials, filters, sensors, actuators and multifunctional devices. 21–23…”
It is well-known that traditional Buckypaper (BP) is composed of a certain number of short carbon nanotubes (CNTs) intertwined with each other and sliding always happens when BP is under...
“…These materials have common applications in supercapacitors as well as other electrochemical fields such as electrodes for fuel cells, batteries, and electrolyzers. [27][28][29][30][31][32][33] PPy belongs to a special class of polymers known as conductive polymers. A conjugated network in the polymer backbone allows charge to travel along the chain.…”
A simple approach to mitigate the use of high voltages on thin bipolar electrodes is described here for the first time. The method involves stacking the desired thin conductor onto a thicker one, thereby creating a pseudo-single electrode whose width is the sum of the two. Placing the target material on the positive or negative face of the combined bipolar electrode selects which reaction it will be involved in. This method is used to graft sheets of carbon paper, cloth, and buckypaper with an aminophenyl layer that subsequently binds polypyrrole in a simple two stage reaction to create a one-sided deposit of a supercapacitive material. By itself the necessary driving potential for these reactions exceed 90 V, while with the stack it drops to 9 V. The resulting supercapacitor electrodes display good performance, with specific capacitances up to 210 mF/cm 2 and lasting 2500 charge/discharge cycles.
“…Supercapacitors (SCs), also known as electrochemical capacitors, have been widely studied for alternative energy storage devices because they possess high power capabilities, high charge/discharge rates, and very long cycle-life [1][2][3][4][5][6]. However, SCs still have a low energy density and are not yet practical applications.…”
This study presents a high porous nanocomposite composed of reduced graphene oxide and NiMoS4 (RGO/NiMoS4) for supercapacitor electrode materials. The different morphologies of NiMoS4 growth on RGO sheets were obtained via a facile one-step microwave-assisted method. The obtained material comprised NiMoS4 nanoneedles of several nanometers in diameter, which are well attached to the surface of RGO nanosheets. The RGO/NiMoS4 nanocomposite had a mesoporous structure, high specific surface area, and high electric conductivity. These excellent characteristics yield a fast electron and ion transport, and a large number of electroactive sites. The RGO/NiMoS4 composite delivered a specific capacitance of 1273 F g−1 at a current density of 1.0 A g−1, high-rate capability of 71.3% retention from 1 to 6.5 A g−1. Besides, an asymmetric supercapacitor device had a capacitance of 80 F g−1 at a current density of 1.0 A g−1 and an energy density of 82.5 Wh kg−1 at a power density of 1000 W kg−1 with an operating voltage of 1.6 V. Thus, the current RGO/NiMoS4 nanocomposite has a great potential for energy storage application.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.