Infrared (IR) detectors play crucial roles in various applications. A significant milestone in advancing next-generation low-cost silicon technology involves the enhancement of hyperdoped black silicon (b-Si) photodetectors, particularly within the infrared (IR) wavelength range. In this study, highly selenium (Se)-doped black (b-Si) silicon photodetectors. Optimizing the laser parameters and diode properties achieved a remarkable 100-fold improvement in responsivity (R), external quantum efficiency (EQE), and specific detectivity (D*) within the long-wave infrared range, with a D* of 1.3 × 1012 Jones at 9.5 μm. Additionally, the Se: b-Si photodetectors maintain a D* of approximately 1.3 × 1011 Jones at critical optical telecommunications wavelengths of 1.3 μm and 1.5 μm. These results indicate a significant stride in IR photodetector technology, offering profound insights into the distinct behaviors of hyperdoped silicon and charting the course for the development of highly efficient IR detectors.