We discuss the capture mechanism into t h e D-ground state of the so-called DX centre in AI,Ga, _,As. Using experimental data for the thermally activated capture of electrons on DX centres in Si-doped AI,Ga, -.As samples in t h e region of x e 0.3 under pressure, we show that, if the emission from t h e intermediate neutral state of DX centres is activated, then an upper limit can be set for the value of the emission activation energy in Si-doped AI,,,Ga,.,As:Aem < 150 meV. This value is much less than the activation energy seen in DLTS, which is t h e activation energy for the emission from the negative ground state AEe& In emission experiments such as DLTS performed in Si-doped AI,Ga, _.As, both electrons are emitted practically at the same time.This paper was presented at the International Symposium on DX Centres and Other Metastable Defects in Semiconductors held at Mauterndorf, Austria, on 18-22 February 1991, but was received by the publisher lno late for inclusion in the special issue of this journal (volume 6, number IOB,