“…In an attempt to resolve challenge (i), germanium (Ge), which has a lattice constant perfectly matched to GaAs (0.07% at 300 K) and superior electron and hole mobility compared with Si, can be grown on Si to provide a buffer layer for integration and fabrication of GaAsbased devices on a Si substrate. [12][13][14][15] Since Ge and GaAs have diamond and zincblende structure, respectively, two possible sublattice allocations are possible for the GaAs layer, although they have exactly the same crystal structure. In one allocation, Ga atoms occupy the face-centered cubic (FCC) sublattice containing the cubic corners, whereas in the other allocation, As atoms occupy this FCC sublattice.…”